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Article
Targeted ferritinophagy in gastrointestinal cancer: from molecular mechanisms to implications
Gastrointestinal cancer is a significant global health burden, necessitating the development of novel therapeutic strategies. Emerging evidence has highlighted the potential of targeting ferritinophagy as a pr...
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Article
Stable Au nanoparticles confined in boron nitride shells for optimizing oxidative desulfurization
Supported gold (Au) nanocatalysts have long played an important role in numerous heterogeneous catalysis. However, the dominant difficulty of poor thermodynamic stability hampers its practical application. Her...
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Article
Open AccessHelicobacter pylori-induced aberrant demethylation and expression of GNB4 promotes gastric carcinogenesis via the Hippo–YAP1 pathway
Helicobacter pylori (H. pylori) infection causes aberrant DNA methylation and contributes to the risk of gastric cancer (GC). Guanine nucleotide-binding protein subunit beta-4 (GNB4) is involved in various tumori...
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Article
Engineering the electronic and geometric structure of VOx/BN@TiO2 heterostructure for efficient aerobic oxidative desulfurization
Particle size governs the electronic and geometric structure of metal nanoparticles (NPs), sha** their catalytic performances in heterogeneous catalysis. However, precisely controlling the size of active met...
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Reference Work Entry In depth
Ionic Liquids for Extractive Desulfurization of Fuels
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Living Reference Work Entry In depth
Ionic Liquids for Extractive Desulfurization of Fuels
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Article
Phosphomolybdic ionic liquid supported hydroxyapatite for heterogeneous oxidative desulfurization of fuels
With the continual air pollution and environmental issues caused by the combustions of sulfur-containing fuels, the desulfurization in transport fuels becomes a crucial topic worldwide. In this study, a kind o...
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Article
Open AccessHarnessing strong metal–support interactions via a reverse route
Engineering strong metal–support interactions (SMSI) is an effective strategy for tuning structures and performances of supported metal catalysts but induces poor exposure of active sites. Here, we demonstrate...
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Article
Supported phosphotungstic-based ionic liquid as an heterogeneous catalyst used in the extractive coupled catalytic oxidative desulfurization in diesel
In order to effectively catalyze the oxidation of dibenzothiophene (DBT) in diesel, a phosphotungstic-based ionic liquid (IL) supported catalyst [C16mim]3PW12O40/TiO2 was prepared through a one-step method. Comme...
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Article
Synthesis of WO3/mesoporous ZrO2 catalyst as a high-efficiency catalyst for catalytic oxidation of dibenzothiophene in diesel
The catalyst of WO3 highly dispersed on mesoporous ZrO2 was prepared by hydrothermal treatment and calcination. Ionic liquid templates with different cations and various calcination temperatures were taken into a...
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Article
Open AccessFabrication of oxygen-defective tungsten oxide nanorods for deep oxidative desulfurization of fuel
Owing to the increasingly serious environmental issues caused by the sulfur burnt in fuel, desulfurization has become an important topic. In this work, an amphiphilic oxygen-defective tungsten oxide was synthe...
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Article
Open AccessSynthesis of amphiphilic peroxophosphomolybdates for oxidative desulfurization of fuels in ionic liquids
Three amphiphilic peroxophosphomolybdates [C4mim]3PMo4O24, [C8mim]3PMo4O24 and [C16mim]3PMo4O24 were synthesized and characterized. These catalysts were used for extraction and catalytic oxidative desulfurization...
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Article
Open AccessCatalytic oxidative desulfurization of fuels in acidic deep eutectic solvents with [(C6H13)3P(C14H29)]3PMo12O40 as a catalyst
Deep eutectic solvents (DESs) are a new class of green solvents analogous to ionic liquids due to their biodegradable capacity and low cost. However, the direct extractive desulfurization of diesel oil by DESs...
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Article
Open AccessPolyoxometalate-based silica-supported ionic liquids for heterogeneous oxidative desulfurization in fuels
With the aim of deep desulfurization, silica-supported polyoxometalate-based ionic liquids were successfully prepared by a one-pot hydrothermal process and employed in heterogeneous oxidative desulfurization o...
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Article
Analysis of the affinity of influenza A virus protein epitopes for swine MHC I by a modified in vitro refolding method indicated cross-reactivity between swine and human MHC I specificities
In vitro refolding assays can be used to investigate the affinity and stability of the binding of epitope peptides to major histocompatibility complex (MHC) class I molecules, which are key factors in the pres...
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Article
Open AccessAmorphous TiO2-supported Keggin-type ionic liquid catalyst catalytic oxidation of dibenzothiophene in diesel
Supported ionic liquid (IL) catalysts [Cnmim]3PMo12O40/Am TiO2 (amorphous TiO2) were synthesized through a one-step method for extraction coupled catalytic oxidative desulfurization (ECODS) system. Characterizati...
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Article
Open AccessTaming interfacial electronic properties of platinum nanoparticles on vacancy-abundant boron nitride nanosheets for enhanced catalysis
Taming interfacial electronic effects on Pt nanoparticles modulated by their concomitants has emerged as an intriguing approach to optimize Pt catalytic performance. Here, we report Pt nanoparticles assembled ...
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Article
Structure and catalytic oxidative desulfurization properties of SBA-15 supported silicotungstic acid ionic liquid
A supported catalyst was synthesized on the mesoporous materials with ionic liquid modified by the silicontungstic acid (HSiW-IL/SBA-15). A series of characterization, such as XRD, N2 adsorption desorption, SEM, ...
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Article
Fabrication of functional dual-mesoporous silicas by using peroxo-tungstate ionic liquid and their applications in oxidative desulfurization
A novel strategy has been applied for synthesis of bimodal mesoporous silica by ionic liquid [C16mim]2[W2O3(O2)4] as a single template as well as tungsten source to incorporate tungsten species onto mesoporous si...
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Article
Photocatalytic oxidative desulfurization of dibenzothiophene catalyzed by amorphous TiO2 in ionic liquid
Three types of TiO2 were synthesized by a hydrolysis and calcination method. The catalysts were characterized by X-ray powder diffraction (XRD), diffuse reflectance spectrum (DRS), Raman spectra, and X-ray photoe...
