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Article
Reaction mechanisms of riboflavin triplet state with nucleic acid bases
ESR and laser flash photolysis studies have determined a reasonable order of reactivity of nucleotides with triplet riboflavin (3Rb*) for the first time. ESR detection of triplet state reactivity of Rb with nucle...
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Article
A pulse radiolysis study on electron affinity of piperonal
The piperonal electron affinity was studied using pulse radiolysis technique. The electron transfer reaction process between piperonal and anthraquinone-2-sulfate was observed in the pH 7 phosphoric acid salt ...
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Article
Dynamic study of photosensitized one-electron oxidation of polyG by menadione
The electron transfer reaction of triplet menadione (3MQ*) with polyguanylic acid (polyG) in CH3CN rich (97%) solution was investigated by 248 nm(KrF) laser flash photolysis. The transient absorption spectra and ...
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Article
Time resolve study on isopropyl-ether porphyrindiol
A novel fat-soluble porphyrin derivative—isopropyl-ether porphyrindiol (IPEP) has been investigated using the nanosecond laser photolysis and pulse radiolysis. In acetonitrile, IPEP-excited triplet state shows...
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Article
Laser photolysis of interaction of poly-guanylic acid (5′) with anthraquinone-2-sulfonate
The electron transfer reaction between triplet anthraquinone-2-sulfonate and polyguanylic acid (5′) in CH3CN-H2O (97?3) has been investigated by 248 nm (KrF) laser flash photolysis. The transient absorption spect...
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Article
Fast repair of dAMP hydroxyl radical adduct by verbascoside via electron transfer
DNA damaged by oxygen radicals has been implicated as a causative event in a number of degenerative diseases, including cancer and aging. So it is very impotant to look for ways in which either oxygen radicals...
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Article
Fast electron transfer repair of oxidizing OH adduct of dGMP by chlorogenic acid
Pulse radiolysis of chlorogenic acid (CGA) as well as CGA and 2′-deoxyguanosine-5′-monophosphate (dGMP) has been carried out in aqueous solution using pulse radiolytic technique. From detailed kinetic analyses...
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Article
Laser flash photolysis of fullerols of C60 and of C70 in aqueous solutions
Fullerols of C60 and of C70 [C60(OH)n, C70(OH)m], water-soluble fullerene derivatives, unlike some other fullerene derivatives (such as C60 (C4H6O), C60 (C3H7N) and C60 [C(COOEt)2]x), do not result in excited tri...
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Article
Reactions of tea polyphenol four constituents with hydroxyl radical: A pulse radiolytic study
Using the electron pulse radiolytic techniques, the reactions between hydroxyl radical and tea polyphenol four constituents epigallocatechin gallate (EGCG), epicatechin gallate (ECG), epigallocatechin (EGC) an...