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Article
High-temperature diffusion of phosphorus and boron in silicon via vacancies or via self-interstitials?
The paper re-examines the effect of oxidation on the diffusion of phosphorus and boron in silicon as well as recent results on redistribution phenomena of these dopants under irradiation and on the emitter-pus...
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Article
The influence of intrisic defects on the degradation and luminescence of GaAs and other III–V compounds
A significant contribution to the degradation of GaAs-based lasers and light-emitting diodes arises from the formation of so-called dark line defects. It is shown that these defects are accumulations of non-ra...
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Article
Mechanism and kinetics of the diffusion of gold in silicon
The diffusion of Au in Si is known to take place via the interchange of Au atoms between substitutional (Au s ) and interstitial (Au i ) sites. ...
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Article
Differences between the Growth Kinetics of Thin Film and Bulk Diffusion Couples
It is proposed that interface reaction barriers in binary A/B diffusion couples lead to the absence of phases predicted by the equilibrium phase diagram, provided that the diffusion zones are sufficiently thin...
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Article
Oxygen diffusion and thermal donor formation in silicon
The information available on the diffusion of oxygen and on the formation of thermal donors in silicon is critically reviewed. In this context the effects of intrinsic point defects on the diffusion-controlled...
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Article
Effect of Concentration Gradient on Phase Stability
A feature of thin film reaction that is different from the reaction in bulk samples is the tendency to form a single intermetallic compound rather than all of them which are allowed according to the equilibriu...
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Article
Thermal Donor Formation by the Agglomeration of Oxygen in Silicon
We suggest that thermal donor formation in silicon involves fast-diffusing, gas-like molecular oxygen in dynamical equilibrium with atomic oxygen in interstitial position. We will discuss still remaining diffi...
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Article
The Nature of Point Defects and their Influence on Diffusion Processes in Silicon at High Temperatures
The paper highlights recent progress in understanding the role of vacancies and self-interstitials in self- and impurity diffusion in silicon above about 700°C. How surface oxidation of silicon leads to a pert...
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Article
On the nature of point defects and the effect of oxidation on substitutional dopant diffusion in silicon
An extensive analysis of the substitutional dopant diffusion phenomena in silicon during oxidation is presented. The analysis covers qualitative as well as quantitative aspects of the oxidation-enhanced and -r...
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Article
The Influence of Point Defects on Diffusion and Gettering in Silicon
In a first part, we deal with the influence of intrinsic point defects (vacancies and self-interstitials) on self- and impurity diffusion in silicon. Estimates of the diffusivities and thermal equilibrium conc...
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Article
Enhanced Carbon Diffusion in Silicon During 900°0 Annealing
Enhanced diffusion of carbon is observed to be produced during annealing of silicon at 900°C under conditions of surface oxidation and phosphorus in-diffusion. Silicon containing high concentrations of carbon ...
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Article
Point defects, diffusion processes, and swirl defect formation in silicon
The paper consists of three parts. In the first part we review the basic experimental and theoretical results which shaped our present knowledge on point defects and diffusion processes in silicon. These resul...
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Article
The Role of Carbon and Point Defects in Silicon
An overview of the behavior of intrinsic point defects in silicon and their interaction with carbon is given for temperatures above about 500° C. The diffusive mechanism of carbon in silicon, which involves si...
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Article
Two-dimensional phosphorus diffusion for soft drains in silicon MOS transistors
Phosphorus has a considerably less steep concentration profile than arsenic. Therefore phosphorus is considered as an alternative dopand for soft drain concepts in future MOS devices. In-diffusion of phosphoru...
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Article
Mechanisms of Do**-Enhanced Superlattice Disordering and of Gallium Self-Diffusion in GaAs
Recently available Ga-Al interdiffusion results in GaAs/AlAs superlattices allow to conclude that Ga self-diffusion in GaAs is carried by triply-negatively charged Ga vacancies under intrinsic and n-do** con...
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Article
Mechanisms of Self-Diffusion and of Do**-Enhancement of Superlattice Disordering in GaAs and AlAs Compounds
An understanding of the mechanisms of self-diffusion and of interdiffusion in the compound materials GaAs and AlAs may be arrived at byt noting the effects of (i) charge, (ii) As pressure, and (iii) point defe...
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Chapter
Diffusion in Semiconductors
Atomic diffusion processes in semiconductors play an important role in the fabrication of electronic devices in various areas. These areas include:
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Article
Do oxygen molecules contribute to oxygen diffusion and thermal donor formation in silicon?
In- and out-diffusion experiments of oxygen in silicon indicate the existence of an oxygen-containing species diffusing much faster than interstitial oxygen at temperatures below about 700°C. The formation of ...
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Article
Diffusion in Gallium Arsenide and GaAs-Based Layered Structures
The mechanisms of Ga self-diffusion can be derived from interdiffusion experiments in intrinsic and doped GaAs-based superlattices. These experiments allow to conclude that Ga self-diffusion in intrinsic and n...
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Article
Growth, shrinkage, and stability of interfacial oxide layers between directly bonded silicon wafers
Models for the growth and shrinkage of an interfacial oxide layer and for the stability of the interfacial oxide layer are formulated. Predictions of these models are compared to results obtained by high-resol...