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Article
Polymetalorganosiloxanes as a Reflection of the Milestones in the Development of Advanced Technologies in the Chemistry of Silicones
This review analyzes the areas of practical application of oligomeric and polymeric organometal siloxanes as reduced fire risk coatings, antifriction and heat-resistant coatings, materials with high refractive...
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Article
Characterization of Superhydrophobic Coatings Based on PDMS and MQ Resin on Textured Surfaces
The paper presents the results of studying coatings based on poly(dimethylsiloxane) rubber cross-linked with MQ resin at different contents of the latter. The PDMS : MQ resin ratios have been taken to be 2 : 1...
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Article
Crystallization of Water Droplets on Modified Coatings Based on Polydimethylsiloxane Rubber Crosslinked with MQ Copolymer
The work is devoted to studying the properties of polydimethylsiloxane rubber crosslinked with MQ copolymer and modified with organosilicon compounds of different architectures: asymmetric stereoregular organo...
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Article
Structure and Properties of Nanocomposites Based on Polyimides with Different Chemical Structures and Metalloalkoxysiloxanes
The morphology and physical properties of nanocomposites based on organosoluble polyimides with different chemical structures are studied. Metalloalkoxysiloxanes that differ in terms of the type of the central...
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Article
Effect of reactionary capable siloxane compatibilizer on the properties of blends of ethylene propylene diene and siloxane rubbers
Polydimethyl(methylvinyl)siloxane with long-chain hydrocarbon fragments was synthesized at a sequence of chemical reactions. The resulting graft copolymer was used as a compatibilizer of ethylene propylene die...
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Article
Influence of an Oxygen-Plasma Flow on Polyimide Nanocomposites
The properties of nanocomposites based on heat-resistant organosoluble copolyimide are studied. The nanocomposites are obtained by the sol−gel technique; nanoparticle formation occurs in situ in the polymer-ma...
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Article
Synthesis and properties of carbosilane dendrimers with perfluorohexyl groups in the outer layer of the molecular structure
Branched perfluorohydrosiloxane with CF3CF2CF2C(CF3)2(CH2)3 groups at the silicon atom was synthesized by a sequence of chemical reactions. The resulting compound was used as a modifying agent for carbosilane den...
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Article
Surface Properties of Low-Generation Polyphenylene Dendrimers
The surface properties were studied for the powders of the first- and second-generation polyphenylene dendrimers based on tetrakis(4-ethynylphen-1-yl)methane and the powders of the first- and third-generation den...
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Article
Structure and properties of nanocomposites based on poly(arylene ether ketones) and metalalkoxysiloxanes
Nanocomposites obtained by in situ filling from amorphous poly(arylene ether ketones) based on 4,4´-difluorobenzophenone and 3,3-bis(4´-hydroxyphenyl)phthalide (phenolphthalein) with hydroxyl or benzophenone end ...
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Article
The effect of hafnium alkoxysiloxane precursor structure of disperse phase on the morphology of nanocomposites based on polyaryleneetherketone
Amorphous polyaryleneetherketone tetrakis(phenyldiethoxysiloxy)hafnium or tetrakis(methyldiethoxysiloxy) hafnium are used as precursors of disperse phase of composites. One of the factors determining the morph...
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Article
Polymer composites with surface modified SiO2 nanoparticles: Structures, properties, and promising applications
Data from recent studies of polymer composites with nanosized silica particles are considered. A comparative analysis of current approaches to the description of concentration changes in the glass-transition t...
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Article
Surface modification of epoxy resin by amphiphilic fluoroorganosiloxane copolymers
An amphiphilic fluoroorganosiloxane copolymer designed for a surface modification of epoxy resin by fluorine-containing fragments has been synthesized. The copolymer contains anchor units with terminal amino g...
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Article
Structure and properties of organic-inorganic nanocomposites based on polyaryleneetherketone
Polyaryleneetherketone (PAEK) based composites obtained by in situ filling method have been investigated. Ethyl silicate, tris-(methyldiethoxysiloxy)iron and tetrakis-(methyldiethoxysiloxy)zirconium were used as ...
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Article
Phase structure and properties of blends based on polystyrene and carbosilane dendrimers
Blends based on polystyrene and first- and third-generation carbosilane dendrimers with dimethyl(2-phenylethyl)silyl)propyl terminal groups are studied. For the same chemical structure of the outer layer, a ch...
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Article
Synthesis of fluorine-containing organosilicon copolymers and their use for the preparation of stable hydrophobic coatings based on the epoxy binder
A series of novel fluorine-containing organosilicon copolymers was synthesized in an excess of acetic acid. The efficiency of their use as hydrophobic agents for epoxy film-forming materials was shown.
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Article
Structure of polylactide-modified silicasol nanocomposites based on thermodynamically compatible components
The possibility of implementing entropic mixing for preparing nanocomposites based on thermodynamically compatible components was studied in this work. Polylactide was used as matrix polymer; molecular silicas...
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Article
Thermodynamic analysis of the glass transition temperatures of the polymer-hybrid nanoparticles systems
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Article
Structure and properties of composites based on polyethylene oxide and molecular silicasol
In this work the possibility of forming nanocomposite materials based on polyethylene oxide and hybrid organo-inorganic “core-shell” systems known as molecular silicasols with a modified external layer is stud...
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Article
Fracture of polystyrene- and molecular silica sol-based nanocomposites during fast compression
Polystyrene-based composites containing hybrid molecular silica sol nanoparticles with a core-shell structure are studied during fast compression. Polystyrene and the related composites are found to fail insta...
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Article
New type of ductile-to-ductile transition in particulate-filled composites