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  1. No Access

    Article

    Synthesis of fluorine-containing organosilicon copolymers and their use for the preparation of stable hydrophobic coatings based on the epoxy binder

    A series of novel fluorine-containing organosilicon copolymers was synthesized in an excess of acetic acid. The efficiency of their use as hydrophobic agents for epoxy film-forming materials was shown.

    M. A. Soldatov, N. A. Sheremet’eva, A. A. Kalinina… in Russian Chemical Bulletin (2014)

  2. No Access

    Article

    Thermodynamics of fluorinated derivatives of carbosilane dendrimers of high generations

    The temperature dependences of the heat capacities of fluorinated derivatives of carbosilane dendrimers of high (4.5 and 7.5) generations were studied by adiabatic vacuum calorimetry in the range from 6 to 340...

    A. V. Markin, Ya. S. Samosudova, N. N. Smirnova… in Russian Chemical Bulletin (2011)

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    Effect of fluorinated substituents on hydrodynamic and conformational properties of hyperbranched polycarbosilane in solutions

    Fractions of hyperbranched polycarbosilane modified with fluorine-containing end groups are studied by the methods of molecular hydrodynamics and optics in dilute solutions in hexafluorobenzene, methyl tert-butyl...

    A. I. Amirova, E. V. Belyaeva, E. B. Tarabukina… in Polymer Science Series C (2010)

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    Article

    Thermodynamics of the sorption of organic vapors in a carbosilane dendrimer and a hyperbranched polymer

    Fluorinated derivatives of the carbosilane G6 dendrimer and the hyperbranched polymer of the same chemical structure are synthesized and characterized via the method of inverse gas chromatography. For various ...

    N. A. Belov, N. A. Sheremet’eva, Yu. P. Yampolskii… in Polymer Science Series A (2009)

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    Article

    Effect of the length of branches on hydrodynamic and conformational properties of hyperbranched polycarbosilanes

    The hydrodynamic and conformational properties of hyperbranched polycarbosilanes with different lengths of branches, namely, poly(methyl(allyl)carbosilane) containing three CH2 groups between branching centers an...

    E. B. Tarabukina, A. A. Shpyrkov, E. V. Tarasova, A. I. Amirova… in Polymer Science Series A (2009)