11 Result(s)
within
Mehdi Fallah-Mehrjardi
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Article
A copper(II) chloride coordination compound with 2-phenyl-4,5-dihydro-1H-imidazole ligand: synthesis, characterization, crystal structure, HSA, and DFT studies
Under ultrasound irradiation in an ethanol solvent, a new coordination complex of Cu(II) was successfully synthesized within a 10-min timeframe through the treatment of an imidazole-based ligand (PDI) with a c...
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Article
Ultrasound irradiation synthesis of novel copper(II) complex with the 2-thiophenimidazoline ligand: SC-XRD, HSA, and DFT study
A novel coordination CuCl2(L)2 complex was synthesized by complexation of the 2-thiophenimidazoline ligand with CuCl2.2H2O in less than 10 min. The synthesis was done using ultrasound irradiation in an ethanol so...
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Article
Synthesis, spectral characterization, and theoretical studies of oxo-peroxo tungsten (VI) Schiff base complex with an isonicotinohydrazone ligand and its application in the selective oxidation of benzylic alcohols
A tungsten (VI) complex, [WO(O2)L(CH3OH)], L = (E)-N'-(2-hydroxy-3-methoxybenzylidene)isonicotinohydrazide has been synthesized by the action of WO3 with a ONO donor tridentate Schiff base using H2O2. The tungste...
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Article
Synthesis, spectral characterization, and theoretical investigation of Ni(II) and Pd(II) complexes incorporating symmetrical tetradentate Schiff base ligand: Suzuki-Miyaura cross-coupling reaction using PdLSym
In the present work, a potential symmetric ONNO-tetradentate chelating ligand (H2LSym) has been utilized to prepare stable Ni(II) and Pd(II) complexes. The ligand was synthesized using 4,5-dimethyl-1,2-phenylened...
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Article
Selective oxidation of benzylic alcohols using Mo(VI) Schiff base complex supported on magnetic nanoparticles as a new recoverable heterogeneous catalyst
In the present study, magnetic nanoparticles were functionalized with a dioxomolybdenum(VI) complex containing the tridentate ONO Schiff base ligand obtained from the condensation reaction of 3-ethoxysalicylal...
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Article
Novel dioxomolybdenum complexes containing ONO-tridentate Schiff base ligands derived from 4-aminobenzohydrazide: synthesis, spectral characterization, and application as efficient homogeneous catalysts for selective sulfoxidation
Novel dioxomolybdenum Schiff base complexes, [MoO2(Ln)(CH3OH)], were synthesized by the reaction of MoO2(acac)2 and ONO donor Schiff base ligands (H2Ln) derived by the condensation of 4-aminobenzohydrazide and su...
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Article
Selective oxidation of benzyl alcohols to benzaldehydes catalyzed by dioxomolybdenum Schiff base complex: synthesis, spectral characterization, crystal structure, theoretical and computational studies
A novel dioxomolybdenum Schiff base complex, MoO2L·DMF, was synthesized by treating MoO2(acac)2 with an ONO donor Schiff base ligand (H2L) derived by the condensation of 4-aminobenzohydrazide and 3-methoxysalicyl...
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Article
Syntheses, characterization, and catalytic potential of novel vanadium and molybdenum Schiff base complexes for the preparation of benzimidazoles, benzoxazoles, and benzothiazoles under thermal and ultrasonic conditions
A new ONO-tridentate Schiff base ligand (H2L) derived from 3-methoxysalicylaldehyde and nicotinic hydrazide was synthesized and characterized by elemental analysis, FT-IR, 1H NMR, 13C NMR, UV–Vis, and powder XRD ...
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Article
Review of the organic trithiocarbonates synthesis
Trithiocarbonates are an important class of organic compounds that have found a wide range of application in industrial and medical chemistry. They have been employed as key precursors, intermediates, or prote...
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Article
Nucleophilic ring-opening of epoxides: trends in β-substituted alcohols synthesis
The present review deals with the ring-opening of epoxides by various carbon, nitrogen, oxygen, halogen, and sulfur-containing nucleophiles, which most of the resulting products are versatile intermediates in ...
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Article
Greener and facile aqueous regioselective synthesis of vicinal azidoalcohols using silica-bound 3-((polyethyleneglycol)ethyl)-8-methyl-1H-imidazol-3-ium bromide as a recyclable catalyst
An environmentally benign, aqueous synthesis of vicinal azidoalcohols by the regioselective nucleophilic ring opening of epoxides with azide anion using silica-bound 3-((polyethyleneglycol)ethyl)-8-methyl-1H-i...
