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Article
Ionic transport in (La,Sr)CoO3-δ ceramics
Increasing Sr2+ concentration and the creation of A-site deficiency in La1-x-ySrxCoO3-δ (x = 0.3–0.7, y = 0–0.05) increase oxygen ionic conductivity, oxygen permeability of the dense ceramic membranes, and surfac...
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Article
Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization
Chemical functionalization is a powerful approach to tailor the physical and chemical properties of two-dimensional (2D) materials, increase their processability and stability, tune their functionalities and, ...
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Article
Transport and Electrochemical Properties of SrFe(Al,Mo)O3–δ
In this work, effects of molybdenum do** on the crystal structure, stability, electrical conductivity, oxygen permeability and thermomechanical properties of Sr(Fe,Al)O3–δ-based perovskites, were studied. The e...
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Article
Defect formation, ordering, and transport in SrFe1–x Si x O3–δ (x = 0.05–0.20)
Oxygen nonstoichiometry of perovskite-like SrFe1–x Si x O3–δ (x = 0.05–0.20), studied by thermogravimetric analysis and coulometric titration in ...
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Article
Grain-boundary states in solid oxide electrolyte ceramics processed using iron oxide sintering aids: a Mössbauer spectroscopy study
In order to appraise microstructure-determined defect formation processes and minor intergranular states in the solid electrolyte materials sintered employing transition metal oxide additives, the transmission...
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Article
Ion transport in dual-phase SrFe1−xТаxO3−δ (x = 0.03 − 0.10): effects of redox cycling
The incorporation of tantalum cations in mixed-conducting SrFe1-xTaxO3−δ (x = 0.03 − 0.10) results in the formation of single cubic perovskite-like phases in oxidizing atmospheres while under red...
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Article
Insertion of iron oxide in calciumsilicate gel-derived materials
Samples of the composition of 10Fe2O3·10CaO·80SiO2 were prepared by the sol-gel method and heat-treated in different atmospheres. They were investigated by X-ray diffraction, scanning electron microscopy and Möss...
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Article
Mössbauer Spectra and Catalytic Behaviorof Perovskite-like SrFe0.7Al0.3O3-δ
Mixed-conducting SrFe0.7Al0.3O3-δ (SFA) exhibits substantial catalytic activity towards partial oxidation of methane and can thus be considered as a component of monolithic ceramic reactors for synthesis gas gene...
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Article
Defect formation and transport in SrFe1-xAlxO3-δ
Perovskite-related phases derived from SrFeO3-δ are among known mixed conductors with highest oxygen permeability and are thus of interest as the ceramic membrane materials for oxygen separation and partial oxida...
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Article
Properties of CaTi1 − xFe x O3 − δ Ceramic Membranes
CaCO3, TiO2 and Fe2O3 were mixed in the appropriate stoichiometric quantities and calcined at 1100∘C for 10 h. These powder mixtures were uniaxially pressed and sintered at temperatures ranging from 1350 to 1500_...
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Chapter
Non-Fermi Liquid Behavior in U3-xNi3Sn4-ySingle Crystals
The behavior of an increasing number of metallic, paramagnetic 4f-and 5f-electron systems are known to be inconsistent with simple Fermi liquid theory. Although magnetic order is the typical groundstate for ra...
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Article
Powder XRD structure refinements and 57Fe Mössbauer effect study of synthetic Zn1-xFexAl2O4 (0 < x ≦ 1) spinels annealed at different temperatures
Members of the solid solution series Zn1-x Fe x Al2O4 (x = 0.2, 0.4, 0.6 and 1.0) with spinel structure were synthesized by direct solid-state reaction of the simple metal oxides...
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Article
X-ray powder diffraction and57Fe Mössbauer spectroscopy study of the thermal breakdown of vivianite, Fe3(PO4)2.8H2O
Ferric phosphates resulting from the thermal breakdown of natural Fe3(PO4)2.8H2O are studied by X-ray powder diffraction and Mössbauer spectroscopy. Total iron oxidation and water release give rise to an amorphou...