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Article
Hydrogen Production from Methane with CO2 Utilization over Exsolution Derived Bimetallic NiCu/CeO2 Catalysts
Hydrogen production from methane with CO2 utilization over exsolution derived NiCu/CeO2 catalysts was studied. To form highly dispersed supported bimetallic NiCu particles the Ce0.75(NiCu)0.25O1.75 catalyst precu...
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Article
GENESIS AND STRUCTURAL PROPERTIES OF (Ce1–xMx0.8Ni0.2Oy (M = La, Mg) OXIDES
The genesis and structural properties of (Ce1–xMx)0.8Ni0.2Oy (M = La, Mg; x = 0, 0.2, 0.5, 0.8, 1; 1.0 ≤ y ≤ 1.8) oxides that are promising catalyst precursors are studied. A complex of physicochemical methods (l...
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Article
Formation and Properties of Ni–Ce–La–O Catalysts of Reforming
In order to stabilize in the support matrix highly dispersed nickel forms of the active component, which are characterized by thermal stability and high resistance to carbonization under conditions of hydrocar...
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Article
Effect of Preparation Methods on the Physicochemical and Functional Properties of Ni/CeO2 Catalysts
The effect of preparation procedures (a polymer ester precursor method and incipient wetness impregnation) on the physicochemical and functional properties of Ni/CeO2 catalysts with different nickel contents (0–1...
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Article
Open Access5D operando tomographic diffraction imaging of a catalyst bed
We report the results from the first 5D tomographic diffraction imaging experiment of a complex Ni–Pd/CeO2–ZrO2/Al2O3 catalyst used for methane reforming. This five-dimensional (three spatial, one scattering and ...
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Article
Ethylene production by the oxidative condensation of methane in the presence of MnMW/SiO2 catalysts (M = Na, K, and Rb)
The samples of MnMW/SiO2 (M = Na, K, and Rb) were synthesized using various synthesis methods under varied heat treatment conditions and their physicochemical properties and activity in the reaction of the oxidat...
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Article
Effect of the support composition on the physicochemical properties of Ni/Ce1–x La x O y catalysts and their activity in an autothermal methane reforming reaction
The effect of the Ce1–x La x O y (x = 0–1, 1.5 ≤ y ≤ 2.0) support composition on the physicochemical properties...
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Article
Development of a Ni–Pd/CeZrO2/Al2O3 catalyst for the effective conversion of methane into hydrogen-containing gas
The effects of the Pd content (0–1 wt %) and the synthesis method (joint impregnation with Ni + Pd and Pd/Ni or Ni/Pd sequential impregnation) on the physicochemical and catalytic properties of Ni–Pd/CeZrO2/Al2O3
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Article
Structural and morphological properties of Ce1–x M x O y (M = Gd, La, Mg) supports for the catalysts of autothermal ethanol conversion
A complex of physicochemical methods (powder XRD analysis, transmission and scanning electron microscopy, electron spectroscopy of diffuse reflectance, low-temperature nitrogen adsorption) is used for the comp...
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Article
Oxidative condensation of methane in the presence of modified MnNaW/SiO2 catalysts
The effects of cationic (Ce, Zr, and La) and anionic (S, P, and Cl) admixtures on the activity and physicochemical properties of MnNaW/SiO2 were studied in order to optimize the composition of a catalyst for the ...
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Article
Effect of support modification on the physicochemical properties of a NiPd/Al2O3 catalyst for the autothermal reforming of methane
For the development of effective catalysts for the autothermal reforming of methane, the NiPd catalysts were synthesized based on modified aluminum oxide and their physicochemical properties were studied using...
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Article
Synthesis of mesoporous bimetallic Pt-Sn catalytic coatings from polynuclear precursors for fine organic synthesis processes
A new method is developed to obtain nanosized catalytic Pt-Sn/TiO2 coatings on the inner surface of a capillary microreactor during adsorption of polynuclear carbonyl Pt-Sn complexes on mesoporous TiO2. Titanium ...
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Article
Synthesis of nanosized thin-film bimetallic catalysts based on mesoporous TiO2 for microstructured reactors
A synthetic procedure for the production of effective catalysts for the selective hydrogenation of organic substrates was developed, and the samples of thin-film Pt-Sn/TiO2 materials, which are characterized by h...
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Article
Methane conversion to valuable chemicals over nanostructured Mo/ZSM-5 catalysts
Results of the ongoing study of nonoxidative methane dehydroaromatization (DHA) over Mo/ZSM-5 catalysts have been analyzed. The effects of the composition, preparation procedure, pretreatment, and the CH4 DHA rea...
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Article
Synthesis of nitrogen-containing carbon materials for solid polymer fuel cell cathodes
The following nitrogen-containing supports with various nitrogen contents and structure and texture properties were synthesized: carbon nanofibers (N-CNFs) and amorphous microporous carbon materials (N-AMCMs)....
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Article
A Comparative Study of the Activity of Oxide Catalysts in the Oxidation of Methane and 1,1-Dimethylhydrazine
The catalytic oxidation of methane and 1,1-dimethylhydrazine ((CH3)2N–NH2, unsymmetrical dimethylhydrazine (UDMH)) with air on oxide catalysts was studied. Two pairs of perovskites (Ca0.7Sr0.3FeO2.5(3.0) and La0....
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Chapter and Conference Paper
Oxidation of Unsymmmetrical Dimethyl Hydrazine over Oxide and Noble Metal Catalysts. Solution of Environmental Problems of Production, Storage and Disposal of Highly Toxic Rocket Fuels
Reduction and conversion of weapons production in Russia have made extremely urgent the problems of development and implementation of environmentally safe and efficient processes of disposal of rocket fuel com...