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Open AccessAuthor Correction: Direct fermentative conversion of poly(ethylene terephthalate) into poly(hydroxyalkanoate) by Ideonella sakaiensis
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Article
Multiple comonomer concentrations prediction from FTIR spectra with quantum chemistry-based interpretation
In this study, we enhance our previously proposed modeling approach, which combines wavelet transform and linear regression and utilizes Fourier transform infrared spectroscopy spectra, to simultaneously estim...
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Article
Investigation of the mechanical properties and degradation of ester-free poly(trimethylene carbonate) derivatives bearing various bulky aromatic groups
Ester-free trimethylene carbonate derivatives bearing bulky aromatic groups were designed and synthesized, including those with one or two benzyl groups, diphenylmethyl groups, and triphenylmethyl groups. The ...
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Article
Preparation of poly(N-vinyl caprolactam) with various end groups using chain transfer agents and evaluation of their effects on kinetic hydrate inhibition
Poly(N-vinylamide) derivatives were synthesized to improve the performance of kinetic hydrate inhibitors (KHIs). In this work, we synthesized poly(N-vinylformamide) (PNVF) and poly(N-vinylcaprolactam) (PVCap) by ...
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Article
Radical copolymerization on fluoroalkyl α-chloroacrylate monomers for copolymer composition control
The radical copolymerization on α-substituted fluoroalkyl acrylate (FA) monomer bearing C4, C6, and C8 as perfluoroalkyl (Rf) groups, as well as the variation of α-substituents, hydrogen, methyl, and chlorine wit...
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Article
Preparation and analyses of stereocomplexes of a polylactide homopolymer and copolymer with poly(ethylene glycol) and urethane cap**
Polylactide (PLA) stereocomplexes (SCs) formed by poly(L,L-lactide) (PLLA) and poly(D,D-lactide) (PDLA) are well known, and their derivatives and copolymers have also been reported. However, little research ha...
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Article
Open AccessDirect fermentative conversion of poly(ethylene terephthalate) into poly(hydroxyalkanoate) by Ideonella sakaiensis
Poly(ethylene terephthalate) (PET) is a widely used plastic in bottles and fibers; its waste products pollute the environment owing to its remarkable durability. Recently, Ideonella sakaiensis 201-F6 was isolated...
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Article
Fabrication of flexible blend films using a chitosan derivative and poly(trimethylene carbonate)
To modify the flexibility of chitosan (CS), poly(trimethylene carbonate) (PTMC) and its derivatives and copolymers were blended with a chitosan derivative, N,N,N-trimethylchitosan (TM-CS). The tensile strength of...
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Article
Glycerol-modified poly(ε-caprolactone): an biocatalytic approach to improve the hydrophilicity of poly(ε-caprolactone)
Novel poly(ε-caprolactone) (PCL)–glycerol polyester was synthesized in one step in the presence of Novozym 435 under mild reaction conditions. The objective of the study was to investigate the feasibility of e...
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Article
The electrostatic advantages of cross-linked polystyrene organogels swollen with limonene for selective adsorption and storage of hydrophobic drugs
The organogels poly(styrene-co-divinylbenzene), PS gel (1); poly(styrene-co-divinylbenzene-co-vinylpyridine), PS-VP gel (2); poly(styrene-co-divinylbenzene-co-vinylbenzoic acid), PS-VBA gel (3); and poly(styrene-
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Article
A novel comb-shaped polymethacrylate-based copolymers with immobilized 2,4-dihydroxybenzaldehyde for antifungal activity
Poly(methacrylic acid-co-2-aminoethyl methacrylate) (MAA-AMA) was simply synthesized by free radical polymerization. Immobilization of 2,4-dihydroxybenzaldehyde on MAA-AMA was done via Schiff base formation to ob...
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Article
Pentaerythritol particles covered by layer-by-layer self assembled thin films with stereocomplex of isotactic poly(methyl methacrylate) and syndiotactic poly(methyl methacrylate)
In this paper, we present a different approach of coating a phase change material (PCM) for a possible use in thermal energy storage. We focused on layer-by-layer coating of pentaerythritol (PE) particles, whi...
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Article
Open AccessAggregation Control by Multi-stimuli-Responsive Poly(N-vinylamide) Derivatives in Aqueous System
Thermal and photo responsive copolymer based on N-vinylamide backbone was designed. Methoxyethyl group and azobenzene were selected to improve hydrophilicity and photoresponsive moieties, respectively. The N-(met...
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Article
Thermally resistant polylactide layer-by-layer film prepared using an inkjet approach
The inkjet printing technique is potentially applicable for the formation of polymer stereocomplexes and can control the amount, thickness and structure of the printed polymers. Stereocomplexes of polylactides...
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Article
Polymer design using trimethylene carbonate with ethylene glycol units for biomedical applications
Poly(trimethylene carbonate) (PTMC) is a biodegradable polymer that is used in biomedical materials. It has been reported that its combination with hydrophilic groups such as oligo(ethylene glycol) and poly(et...
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Article
A novel substrate for testosterone: biodegradable and biocompatible oil gel
The androgen testosterone is less expensive than bone morphogenetic proteins and has been shown to effectively repair bone fractures. However, testosterone is lipophilic and insoluble in water, making it diffi...
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Reference Work Entry In depth
Template Polymerization (Molecular Templating)
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Living Reference Work Entry In depth
Template Polymerization (Molecular Templating)
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Article
Synthesis of a thermosensitive polycation by random copolymerization of N-vinylformamide and N-vinylbutyramide
The novel thermoresponsive polycations poly(N-vinylbutyramide-co-vinylamide) (poly(NVBA-co-VAm)), with different mole ratios of poly(VAm) (PVAm):poly(NVBA) (PNVBA), were synthesized as a biomaterial by free radic...
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Article
A study on template effects using irregular porous isotactic poly(methyl methacrylate) films constructed with syndiotactic rich poly(methacrylic acid) and isotactic poly(methyl methacrylate)
To investigate the stereocomplex formation efficiency with various syndiotactic-poly(methacrylic acids) (st-PMAAs) after the extraction of the syndiotactic-rich PMAA from stereocomplex film, the low syndiotactici...