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Article
Molecular species of sphingomyelin in sphingomyelinase-sensitive and sphingomyelinase-resistant pools of HL-60 cells
This study of sphingomyelin molecular species in undifferentiated and differentiated (granulocytic form) HL-60 cells demonstrated only minor differences in the distribution of species between the sphingomyelin...
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Article
Chemical synthesis and physiological activity of sulfonium analogues of platelet activating factor
Phosphatidylsulfocholine (PSC), the sulfonium analogue of phosphatidylcholine (PC), occurs naturally in some diatoms. The replacement of the −N+(CH3)3 group by a −S+(CH3)2 results in an increase in the polar head...
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Article
Dietary supplementation with ether-linked lipids and tissue lipid composition
The goal of this investigation was to determine the effect of an alkylglycerol dietary supplement on the lipid composition of several major organs. Lipids from kidney, liver, and lung tissues of rats on a labo...
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Article
Phase transition of an unnatural analog of phosphatidylcholine: Phosphatidyl-N-isopropylethanolamine
The phase-transition temperature, of an aqueous dispersion of dipalmitoyl phosphatidyl-N-isopropylethanolamine was determined was determined usingtrans-parinaric acid as a fluorescent probe. Phosphatidyl-N-isopro...
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Article
Occurrence of ethanolamine- and choline-containing plasmalogens in adipose tissue
Analysis of phospholipids in porcine, bovine and rat adipose tissue revealed a relatively high level of plasmalogens (O-alk-1-enyl lipids). About 50% of the ethanolamine phospholipids in the pig and beef samples ...
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Article
Structural relationships between glycerides of pig serum and adipose tissue
Structural analyses have been performed on the triacylglycerols and phosphoglycerides isolated from adipose tissue, serum chylomicrons, and serum lipoproteins from pigs. The triacylglycerols from adipose tissu...
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Article
Long chain fatty alcohols in normal and neoplastic tissues
Small quantities of long chain fatty alcohols (esterified or free or both) were found in four normal tissues (about 0.01% of total neutral lipids) and three neoplasms (about 0.3% of total neutral lipids). The ...
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Article
The quantitative production of aldehydes from O-alk-1-enyl glycerols
The quantitative recovery and structural alterations of aldehydes liberated from O-alk-1-enyl glycerols on thin layer chromatographic layers have been evaluated by using14C-labeled fatty aldehydes and chromatogra...
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Article
Quantitative determination of alk-1-enyl- and alkyl-glyceryl ethers in neutral lipids and phospholipids
A quantitative method for the simultaneous determination of alk-l-enyl- and alkyl-glyceryl ethers is described. Complete hydrogenolysis of carboxylate and phosphate esters of neutral lipids and phospholipids w...
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Article
Lipid droplets and glyceryl ether diesters in ehrlich ascites cells grown in tissue culture
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Article
Chemical and physical properties of isomeric glyceryl monoethers
Long-chain saturated and mono- and diunsaturated 1- and 2-glyceryl monoethers were synthesized by reacting 1,2-isopropylidene and 1.3-benzylidene glycerol potassium salts with alkyl halides in the preparation ...
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Article
An unidentified lipid prevalent in tumors
An unidentified lipid was found in five different tumor sources. It was not found in liver, bone marrow or plasma from tumor-bearing animals, nor in the extracellular fluid supporting growth of Ehrlich ascites...
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Article
The GLC and TLC resolution of diastereoisomeric polyhydroxystearates and assignment of configurations
Trifluoroacetate (TFA) derivatives of methyl 12-hydroxystearate, methyl ricinoleate, five positional isomers of methylthreo- anderythro-dihydroxystearate, four diastereoisomeric methyl 9,10–12-trihydroxystearates...
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Article
Metabolism of alpha-alkoxy glyceryl monoethers in rat liver, in vivo and in vitro
An investigation of the metabolism of14C and3H labeled α-isomers of C16 and C18 alkoxy monoethers, administered intravenously and added to liver slices, showed extensive cleavage of the ether bond in rat liver. A...
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Article
The synthesis of14C- and3H-labeled glycerol ethers
The racemic14C-and3H-labeled alpha and beta derivatives of octadecyl glycerol ether (batyl alcohol) and of hexadecyl glycerol ether (chimyl alcohol) of high specific activity were synthesized by treating the appr...
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Article
Gas-liquid chromatographic analysis of long chain isomeric glyceryl monoethers
A quantitative method is described for the gas chromatographic analysis of glyceryl ethers using their trifluoroacetate (TFA) and trimethylsilyl (TMS) ether derivatives. Both derivatives are prepared at room t...