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Article
A single-atom library for guided monometallic and concentration-complex multimetallic designs
Atomically dispersed single-atom catalysts have the potential to bridge heterogeneous and homogeneous catalysis. Dozens of single-atom catalysts have been developed, and they exhibit notable catalytic activity...
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Article
Morphology of Palladium Thin Film Deposited on a Two-Dimensional Bilayer Aluminosilicate
The morphology of a thin palladium film deposited on bilayer Al0.35Si0.65O2/Ru(0001), previously proposed as a two-dimensional zeolite model, is investigated using a set of complementary spectroscopy and microsco...
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Article
Coupling Ambient Pressure X-ray Photoelectron Spectroscopy with Density Functional Theory to Study Complex Surface Chemistry and Catalysis
Ambient pressure X-ray photoelectron spectroscopy (APXPS) experiments narrow the pressure and materials gaps between UHV surface science experiments and applications. Upon closing these gaps, ambiguity can ent...
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Article
Open AccessSelf-cleaning and surface chemical reactions during hafnium dioxide atomic layer deposition on indium arsenide
Atomic layer deposition (ALD) enables the ultrathin high-quality oxide layers that are central to all modern metal-oxide-semiconductor circuits. Crucial to achieving superior device performance are the chemica...
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Article
Open AccessUnravelling the Chemical Influence of Water on the PMMA/Aluminum Oxide Hybrid Interface In Situ
Understanding the stability of chemical interactions at the polymer/metal oxide interface under humid conditions is vital to understand the long-term durability of hybrid systems. Therefore, the interface of u...
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Article
Open AccessIn Situ Characterization of the Initial Effect of Water on Molecular Interactions at the Interface of Organic/Inorganic Hybrid Systems
Probing initial interactions at the interface of hybrid systems under humid conditions has the potential to reveal the local chemical environment at solid/solid interfaces under real-world, technologically rel...
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Article
Open AccessUHV and Ambient Pressure XPS: Potentials for Mg, MgO, and Mg(OH)2 Surface Analysis
The surface sensitivity of x-ray photoelectron spectroscopy (XPS) has positioned the technique as a routine analysis tool for chemical and electronic structure information. Samples ranging from ideal model sys...
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Article
Crystal Structure of Cis-Dichloro-Bis-{[2-(Diphenylphosphino-κ-P) Methyl]Diphenylphosphine Oxide}Palladium(II) Ethanol Solvate
The title compound cis-Cl2Pd [P(Ph)2PCH2P(O)Ph2]2 crystallizes in the monoclinic space group, P21/c with crystal cell parameters a = 13.076(5) Å, b = 12.931(5) Å, c = 27.465(9) Å, β = 92.661(6)o, V = 4639(3) Å3,