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Effect of ball milling time on the magnetoelectric coupling effect of the multiferroic liquid CoFe2O4–Ba0.8Sr0.2TiO3

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Abstract

In this thesis, CoFe2O4 (CFO) and Ba0.8Sr0.2TiO3 (BST) particles were prepared by chemical co-precipitation and sol–gel methods, respectively. On this basis, the particles were surface modified and then the CFO-BST composite liquid was prepared by adding CFO: BST = 1:1 to the insulating base solution. XRD results showed that pure phase CFO and BST particles were successfully prepared. The maximum dielectric constant and residual polarization intensity were obtained at low frequency (200 Hz) at 30 h. However, the relative rates of change of dielectric constant and ferroelectricity under the action of magnetic field were increasing and then decreasing. At 2 h, the maximum rate of change of magnetic dielectric response (3.15%) and the maximum rate of change of magnetoelectric response (256.4%) were obtained, meanwhile, a coupling coefficient of 8.34 V/(cm Oe) was obtained. This value is several orders of magnitude greater than that of conventional ceramics and promises new applications.

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The structure, dielectric and magnetoelectric effect.

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The datasets and material generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Acknowledgments

The present work has been supported by the Scientific and Technological Research Program of Chongqing Municipal Education Commission (KJZD-M201901501), the Scientific and Technological Research Key Program of Chongqing Municipal Education Commission (KJZD-K20220150), the Chongqing Research Program of Basic Research and Frontier Technology (cstc2019jcyj-msxmX0071, cstc2021jcyj-msxmX0008, cstc2021jcyj-msxmX0039, cstc2021jcyj-msxmX0599), the Program for Creative Research Groups in University of Chongqing (CXQT19031), the Natural Science Foundation of Chongqing (cstc2020jcyj-zdxmX0008, cstc2020jcyj-msxmX0030), the Leading Talents of Scientific and Technological Innovation in Chongqing (CSTCCXLJRC201919), the special project of Chongqing technology innovation and application development (cstc2020jscx-msxmX0218), the Provincial and Ministerial Co-constructive of Collaborative Innovation Center for MSW Comprehensive Utilization, the Scientific and Technological Research Young Program of Chongqing Municipal Education Commission (KJQN202001528), the Research Foundation of Chongqing University of Science and Technology (No. Ckrc2019020), The special project for technological innovation and application development of Chongqing Science and technology enterprises (cstc2021kqjscx-phxmX0008), and the Postgraduate technology innovation project of Chongqing University of Science & Technology (Grant Nos. YKJCX2220205, YKJCX2220222, YKJCX2220224, YKJCX2220230)

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Authors and Affiliations

  1. School of Metallurgy and Materials Engineering, Chongqing University of Science and Technology, Chongqing, 401331, China

    Siqi Zhong, Yulin Zhang, Guiyun Sun, Heng Wu, Hong Ao, Wenchuan Li, Rongli Gao, **aoling Deng, Wei Cai, Zhenhua Wang, Chunlin Fu, **ang Lei & Gang Chen

  2. Chongqing Key Laboratory of Nano/Micro Composite Materials and Devices, Chongqing, 401331, China

    Siqi Zhong, Yulin Zhang, Guiyun Sun, Heng Wu, Hong Ao, Wenchuan Li, Rongli Gao, **aoling Deng, Wei Cai, Zhenhua Wang, Chunlin Fu, **ang Lei & Gang Chen

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  1. Siqi Zhong
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Contributions

SZ: Conceptualization, Methodology, Investigation, Writing—original draft. YZ: Validation, Formal analysis, Visualization. GS: Validation, Formal analysis, Visualization, Writing – review and editing. HW: Validation, Formal analysis,—review and editing. AH: Resources, Writing -review and editing. WL: Resources, Writing—review and editing. RG, XD: Formal analysis, Writing—review and editing. WC, ZW: Writing—review and editing. CF: Resources, Writing—review and editing, Supervision, Data curation. XL: Resources, Writing—review and editing, Supervision, Data curation. GC: Writing—review and editing.

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Correspondence to Rongli Gao or **aoling Deng.

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Zhong, S., Zhang, Y., Sun, G. et al. Effect of ball milling time on the magnetoelectric coupling effect of the multiferroic liquid CoFe2O4–Ba0.8Sr0.2TiO3. Journal of Materials Research 38, 2576–2587 (2023). https://doi.org/10.1557/s43578-023-00987-x

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