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Synthesis, studies of 2-benzyl-amino-4-p-tolyl-6,7-di-hydro 5H-cyclo-penta–[b]pyridine-3 carbo-nitrile (BAPTDHCPCN) crystals for optical, photonic and mechano-electronic uses

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Abstract

2-benzyl-amino-4-P-tolyl-6,7-di-hydro 5H-cyclo-penta –[b]pyridine–3 carbo–nitrile—BAPTDHCPCAN crystal is grown by solution growth evaporation method and analysed for XRD, Unit Cell, Dielectric analysis, UV, Tauc’s plot and fluorescence and mechano studies. The single crystalline XRD data portrays the monoclinic nature of BAPTDHCPCAN with space group P21/c and a, b, c as 8.6828 Å, 17.7283 Å, 12.0403 Å with β as 94.254°. Chemical formula of crystal as C23H21N3. The crystalline dimension is 14 × 12x7 mm3. The dielectric properties of the BAPTDHCPCAN have larger value at low range of frequencies. The phase matching effectiveness is analyzed and found to be 66 mV. The influx value of macro and thin film of BAPTDHCPCAN crystal is 4.2125 microns and 4.4336 microns as mid value before nano shaped influx. Absorption spectral two peaks centered at 248 nm at 325 nm, the band gap of crystal is calculated as 5.0 eV by photonic enhancement and the fluorescence represented emission for 399 nm. The BAPTDHCPCAN crystal is found to have represented –ve photoconductive nature. The BAPTDHCPCAN crystal specimen in of RISE [Reverse Indentation Size Effect] consequence with n greater than 2.

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Funding

No funding arises from any source and the authors share their own equal contribution for synthesis, studies and, etc.

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Authors and Affiliations

  1. Department of Chemistry, A.V.V.M Sri Pushpam College (Autonomous - Affiliated to Bharathidasan University – Tiruchirappalli – 620 024), Thanjavur, 613 503, Tamilnadu, India

    K. Suganya & R. Manikandan

  2. Department of EEE, Sri Ranganathar Institute of Engineering and Technology, Athipalayam, Coimbatore, 641 110, Tamilnadu, India

    J. Maalmarugan

  3. Amrita Vishwa Vidyapeetham, Coimbatore, 641 112, Tamilnadu, India

    T. Sakthi Nagaraj

  4. Department of Pure and Applied Physics, Guru Ghasidas Vishwavidyala, Bilaspur, 495 001, Chhattisgarh, India

    R. P. Patel

  5. Department of Physics, S.T. Hindu College, Nagercoil, 629 002, Tamilnadu, India

    K. Tamilarasi

  6. Department of Physics, Thirumalai Engineering College, Kilambi, Kanchipuram, 631 551, Tamilnadu, India

    M. Vimalan

  7. Department of Physics/R&D, Edayathangudy G.S Pillay Arts and Science College (Autonomous-Affiliated to Bharathidasan University, Tiruchirappalli, 620024), Nagapattinam, 611 002, Tamilnadu, India

    K. SenthilKannan

  8. Visiting Scientist & Visiting Director Research, Phoenix group, Nagapattinam, 611 001, Tamilnadu, India

    K. SenthilKannan

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  1. K. Suganya
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Contributions

SK: Crystal synthesis. MJ: molecular model, Electrical effect study, MR: write up for mechanical. SNT: computational model. PRP: XRD study and write up. TK: Dielectric write up. VM: Photoconductivity and phase matching write up. SK: Influx, Experimental and write up.Overall corrections, submission.

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Suganya, K., Maalmarugan, J., Manikandan, R. et al. Synthesis, studies of 2-benzyl-amino-4-p-tolyl-6,7-di-hydro 5H-cyclo-penta–[b]pyridine-3 carbo-nitrile (BAPTDHCPCN) crystals for optical, photonic and mechano-electronic uses. J Mater Sci: Mater Electron 33, 19320–19330 (2022). https://doi.org/10.1007/s10854-022-08770-0

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