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Detection of the Photoreversibility of NO2-ONO Linkage Isomerization in [Co(NH3)5NO2]Cl(NO3) Crystals by the Photomechanical Response Method
AbstractThe linkage isomerization of NO 2 -ONO (nitro-nitrito) in the complex cation [Co(NH 3 ) 5 NO 2 ] 2+ is a well-studied classical reaction. It is...
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Design of derivatives of FOX-7-based new four-member heterocyclic insensitive high energy density molecules: a theoretical prospectives
BackgroundTheoretical analysis of the novel, insensitive and high-energy density compounds based on the 1,1-dinitro-2,2-diamino-ethylene (FOX-7)...
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Photochromic Reactions in Coordination Compounds
Photochromic coordination compounds can be broadly divided into two different categories according to the photochromic reaction mechanisms,... -
Reaction Types and Mechanisms
The reaction types discussed in this chapter are proton transfer, substitution, oxidation–reduction, oxidative-addition, and isomerization. The... -
Watching Photochemistry Happen: Recent Developments in Dynamic Single-Crystal X-Ray Diffraction Studies
Photoresponsive materials are an important contemporary research area with applications in, for example, energy and catalysis. Mechanistic... -
Benzocaine as a precursor of promising derivatives: synthesis, reactions, and biological activity
Electrophilic and nucleophilic reactions of benzocaine are the most common procedures to construct a library of benzocaine derivatives, which have...
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Selective catalytic reduction of NOx with ethanol and other C1–4 oxygenates over Ag/Al2O3 catalysts: A review
Research results regarding selective catalytic reduction (SCR) of NO x with ethanol and other C 1-4 oxygenates as reductants over silver-alumina...
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Coordination Bonding: Electronic Structure and Properties
Coordination compounds, alternatively called complexes, are systems where metal ions (d-type transition elements or the f-elements, lanthanides and... -
Interplay of thermochemistry and Structural Chemistry, the journal (volume 27, 2016, issues 1-2) and the discipline
The contents of issues 1 and 2 of Structural Chemistry from the calendar year 2016 are summarized in the present review. A brief thermochemical...
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Applications of nuclear magnetic resonance to study the structure of platinum-group metal complexes in aqueous solutions
The review includes comprehensive NMR data on platinum metals ( 99,101 Ru, 103 Rh, 105 Pd, 187 Os, 195 Pt) and ligand donor atoms ( 1 H, 13 C, 14,15 N, 17 O, 19 F...
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Separation and recovery of ruthenium from nitric acid medium by electro-oxidation
Electro-oxidation method was employed for the separation of Ru as RuO 4 vapour, from nitrosyl nitrate and simulated high level liquid waste (SHLLW)...
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Single Crystal and Powder Methods for Structure Determination of Metastable Species
X-ray crystallography as we know it has been in existence for 100 years, since the publication of the paper by the Braggs in 1913, describing the Law... -
Ruthenium sorption as heterometallic complexes with phosphoryl-containing impregnated sorbents
It is shown that the main features of ruthenium extractive recovery with neutral organophosphorus compounds (L) as [RuNO(NO 2 ) 4 ML n ] (M = Zn, Cu, Co,...
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Reaction of nitrogen dioxide with iron tetraphenylporphyrinate nitro complex containing the trans-1-methylimidazole ligand
Electron and IR spectroscopy, as well as the data on the isotopic analog 15 NO 2 , were used for the studies of the reaction of nitrogen dioxide (NO 2 )...
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Inorganic Photochemistry
The fascinating field of inorganic photochemistry is extremely diverse. This chapter discusses some general principles governing light-induced... -
Thermoanalytical study of linkage isomerism in coordination compounds
The non-isothermal differential scanning calorimetry (DSC) experiments revealed that linkage isomerization of both pure trans -[Co(en) 2 (ONO) 2 ]PF 6 ...
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Chemical X-Ray Photodiffraction: Principles, Examples, and Perspectives
X-ray photodiffraction (in the chemical literature also referred to as photocrystallography), which is based on the combination of... -
Grundlagen
Das Studium der Metallkomplexe, ML (M = Metall, L = Ligand), steht im Mittelpunkt der Koordinationschemie. In diesem Kapitel befassen wir uns mit der... -
Rearrangement of N-(3-pyridyl)nitramine
Contrary to other N -(pyridyl)nitramines, the title compound cannot be rearranged to 3-amino-2-nitropyridine or other isomers. Hypothetical products...