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Synthesis of Optically Active Dendrimers Having Chiral Bisphosphine as a Core
First and second generation chiral dendrimers P-1G1, P-2G1, P-1G2 and P-2G2 containing chiral bisphosphine as a core were synthesized via a reaction of chiral bisphosphine compound (S,S)-1 with benzyl ether dendr...
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Article
Synthesis of the Optically Active Polymer Consisting of Chiral Phosphorus Atoms and p-Phenylene-ethynylene Units
We successfully synthesized optically active polymer 4 by using chiral bisphosphine, (S,S)-1,2-bis(boranato(t-butyl)methylphosphino)ethane (S,S)-1, as a key building block. The structure of the polymer was charac...
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Article
Synthesis of organic-inorganic star-shaped polyoxazolines using octafunctional silsesquioxane as an initiator