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Article
Open AccessAggregation-induced emission from optically active X-shaped molecules based on planar chiral [2.2]paracyclophane
An optically active π-stacked molecule was synthesized incorporating planar chiral [2.2]paracyclophane and o-carborane units to impart circularly polarized luminescence and aggregation-induced emission properties...
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Article
Synthesis of optically active through-space conjugated polymers consisting of planar chiral pseudo-meta-disubstituted [2.2]paracyclophane
The polymerization of enantiopure pseudo-meta-diethynyl[2.2]paracyclophane with a diiodobenzene derivative was carried out through Sonogashira-Hagihara cross-coupling. The synthesized polymers consisted of three-...
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Chapter
Circularly Polarized Luminescence (CPL) Based on Planar Chiral [2.2]Paracyclophane
In this chapter, chiroptical properties, especially circularly polarized luminescence (CPL) properties of optically active molecules based on planar chiral [2.2]paracyclophane are mainly introduced. In additio...
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Chapter
Circularly Polarized Luminescence from Planar Chiral Compounds Based on [2.2]Paracyclophane
In this chapter, recent development on molecules emitting intense circularly polarized luminescence (CPL) based on planar chiral [2.2]paracyclophane is described. Optical resolution routes of the planar chiral...
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Article
Comparison of luminescent properties of helicene-like bibenzothiophenes with o-carborane and 5,6-dicarba-nido-decaborane
This article describes comparison of the anchoring effect on electronic properties of the helicene-like bibenzothiophene between o-carborane and 5,6-dicarba-nido-decaborane. The o-carborane and nido-decaborane-fu...
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Article
π-Conjugated polymer-layered structures: synthesis and self-assembly
π-Conjugated polymers capped with a boronic acid end-functional group were synthesized by chain-growth Suzuki–Miyaura polycondensation. The obtained polymers were reacted with a π-stacked-polymer scaffold, develo...
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Article
Open AccessThe relationship between magneto-optical properties and molecular chirality
The chiral nonanuclear Tb(III) clusters [Tb9(sal-(R)-Bt)16(μ-OH)10]+[NO3]− (Tb-(R)-Bt: sal-(R)-Bt=(R)-2-butyl salicylate) and [Tb9(sal-(S)-Bt)16(μ-OH)10]+[NO3]− (Tb-(S)-Bt: sal-(S)-Bt=(S)-2-butyl salicylate) were...
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Article
Synthesis of optically active through-space conjugated polymers consisting of planar chiral [2.2]paracyclophane and quaterthiophene
The alternating copolymers containing planar chiral 4,12-disubstituted[2.2]paracyclophane and quaterthiophene units in the main chain were prepared. The obtained optically active polymers exhibited mirror imag...
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Reference Work Entry In depth
Polyamines
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Reference Work Entry In depth
Carborane Polymers
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Article
Synthesis and characterization of an alternating copolymer with 1,2-disubstituted and 9,12-disubstituted o-carborane units
The alternating copolymer containing p-phenylene-ethynylene, 1,2-disubstituted o-carborane and 9,12-disubstituted o-carborane units in the main chain was prepared. Through the Sonogashira–Hagihara coupling, the d...
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Living Reference Work Entry In depth
Polyamines
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Living Reference Work Entry In depth
Carborane Polymers
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Chapter
Cyclophane-Based π-Stacked Polymers
This chapter focused on the synthesis and fundamental properties of π-stacked polymers, which consist of the stacked π-electron systems created by the [m.n]cyclophane, in particular [2.2]paracyclophane, in the po...
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Article
Synthesis of unsymmetrical P-stereogenic oligophosphines and chemoselective cleavage of phosphine-borane coordinate bonds
This paper describes the synthetic details and coordination abilities of optically active P-stereogenic tetraphosphine and hexaphosphine with different substituted groups on their phosphorus atoms. The polymer...
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Article
Aromatic-ring-layered polymers composed of fluorene and xanthene
Aromatic-ring-layered polymers were synthesized by Sonogashira–Hagihara coupling reaction using xanthene as a scaffold. The polymers were characterized by various spectroscopic and electrochemical methods. The...
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Article
Synthesis and low-temperature dehydrating imidation polymerization of 1,4-dihydro-1,4-diarsininetetracarboxylic acid dianhydride
cis-1,4-Dihydro-1,4-dimethyl-1,4-diarsinine-2,3,5,6-tetracarboxylic acid dianhydride (cis-DHDADA) was quantitatively formed from cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(t-butoxycarbonyl)-1,4-diarsinine (cis
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Article
Naphthalene-based oligothiophene-stacked polymers
We report the synthesis and properties of π-stacked polymers consisting of oligothiophene and naphthalene as the stacked π-system and the scaffold, respectively. The titled polymers were obtained by the Suzuki...
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Article
Aromatic ring-layered polymer containing 2,7-linked carbazole on xanthene
New aromatic ring-layered polymer comprising the 2,7-linked carbazole and xanthene units was synthesized by the Sonogashira coupling reaction. The structure and optical properties of the 2,7-linked carbazole-l...
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Article
Through-space conjugated polymer containing [2.2]paracyclophane and dithiafulvene units in the main chain
A new through-space conjugated polymer containing alternate [2.2]paracyclophane and dithiafulvene units was synthesized by cycloaddition polymerization of aldothioketene derived from 4,16-diethynyl[2.2]paracyc...
