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Article
Solidification of Ni-Re Peritectic Alloys
Differential thermal analysis (DTA) and microstructural and microprobe measurements of DTA and as-cast Ni-Re alloys with compositions between 0.20 and 0.44 mass fraction Re provide information to resolve diffe...
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Article
Examination of Multiphase (Zr,Ti)(V,Cr,Mn,Ni)2 Ni-MH Electrode Alloys: Part I. Dendritic Solidification Structure
The solidification microstructures of three nine-element Zr-Ni–based AB2 type C14/C15 Laves hydrogen storage alloys are determined. The selected compositions represent a class of alloys being examined for usage a...
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Article
Efficient phase diagram information and computational thermodynamics
Industries that process and use metals, from microelectronics to aerospace, can use phase equilibria data for designing and processing complex alloys (three or more components) and diffusion data for controlli...
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Article
Revised thermodynamic description for the Co-Mo system
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Article
On differential thermal analyzer curves for the melting and freezing of alloys
Using a heat-flow model of a differential thermal analyzer and thermal characteristics obtained by fitting experimental results for a pure metal, the response of the differential thermal analyzer is modeled fo...
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Article
Determination of the CoTi congruent melting point and thermodynamic reassessment of the Co-Ti system
New experimental results and a thermodynamic re-evaluation of the Co-Ti system are presented. Using differential thermal analysis (DTA) and a visual observation-of-melting (VOM) technique, the ≈220 K inconsist...
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Article
Moving the pulsed heating technique beyond monolithic specimens: Experiments with coated wires
Pulsed heating experiments that measure high-temperature thermophysical properties using pyrometric measurement of the temperature–time history of metal specimens rapidly heated by passage of electric current ...
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Article
Alpha case thickness modeling in investment castings
The alpha case thickness at the surface of a Ti-6Al-4V (wt pct) step wedge investment casting has been measured and successfully predicted. The prediction uses temperature-time results obtained from a heat flo...
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Article
Experimental and thermodynamic assessment of Sn-Ag-Cu solder alloys
Sn-rich alloys in the Sn-Ag-Cu system are being studied for their potential as Pb-free solders. Thus, the location of the ternary eutectic involving L, (Sn), Ag3Sn and Cu6Sn5 phases is of critical interest. Phase...
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Article
Application of Laser Polarimetry to the Measurement of Specific Heat Capacity and Enthalpy of the Alloy 53Nb–47Ti (mass%) in the Temperature Range 1600 to 2000 K by a Millisecond-Resolution Pulse Heating Technique
The determination of the specific heat capacity, enthalpy, and electrical resistivity of the alloy 53Nb–47Ti (mass%) in the temperature range 1600 to 2000 K is described. The method is based on rapid resistive...
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Article
A thermodynamic assessment of the Ni-Al-B system
The thermodynamics of the Ni-Al-B system are assessed based on available literature data. Both the Ni-B and Al-B systems were revised to treat B as an interstitial element in a face-centered cubic structure, r...
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Article
Thermodynamic assessment of the Co-Mo system
Experimental thermochemical and phase diagram data for the Co-Mo system were assessed. A consistent thermodynamic description, using a Redlich-Kister model for the solution phases and sublattice and line-compo...
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Article
Modeling of micro- and macrosegregation and freckle formation in single-crystal nickel-base superalloy directional solidification
The formation of macrosegregation and freckles by multicomponent thermosolutal convection during the directional solidification of single-crystal Ni-base superalloys is numerically simulated. The model links a...
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Article
A reassessment of the calculated Ni-Nb phase diagram
A revised calculation of the Ni-Nb (nickel-niobium) phase diagram includes realistic enthalpy of formation values for the intermetallic phases that compare with experimental values, a more accurate crystallogr...
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Article
The Al-Bi-Cu system
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Article
Thermodynamic Assessment and Calculation of the Ti-Al System
A thermodynamic description of the Ti-Al system has been developed. Three different analytical descriptions were used to describe the three different types of phases occurring in the Ti-Al system: the stoichio...
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Article
The Al-Cu-Pb system (aluminum-copper-lead)
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Article
The stable and metastable Ti-Nb phase diagrams
The phase transformations which occur in the Ti-Nb binary alloy system have been discussed in two recent papers. The phase relationships were investigated by varying alloy composition and thermal history. In t...