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  1. No Access

    Article

    Hydrodeoxygenation of Sunflower Oil on Pt/WOx-Al2O3 Catalyst

    The authors study the effect of the tungsten oxide in the supports of 0.5% Pt/WOx-Al2O3 catalysts on their acidity, deposited platinum dispersity, and catalytic properties in the hydrodeoxygenation of sunflower o...

    A. A. Nepomnyashchii, V. L. Yurpalov, E. A. Buluchevskiy… in Catalysis in Industry (2024)

  2. No Access

    Article

    Physicochemical and Catalytic Properties of Bifunctional Catalysts with Different Contents of Zeolite ZSM-22 in the Hydrodeoxygenation of Sunflower Oil

    The authors study the effect of the content of zeolite ZSM-22 (15–70 wt %) in a support on the physicochemical properties of Pt/ZSM-22–Al2O3 catalysts. The dependence of the yield and composition of sunflower oil...

    A. A. Nepomnyashchii, E. R. Saibulina, E. A. Buluchevskiy… in Catalysis in Industry (2024)

  3. No Access

    Article

    Combined Deoxygenation and Isomerization of Sunflower Oil Fatty Acid Triglycerides on Pt/Al2O3-Zeolite Catalysts

    The authors study the effect of the type of zeolite (SAPO-11, ZSM-22, ZSM-23, and ZSM-12) in a support (ratio zeolite : Al2О3 = 30 : 70) on the physicochemical properties of Pt/Al2O3-zeolite catalysts and the com...

    A. A. Nepomnyashchii, E. R. Saibulina, E. A. Buluchevskiy… in Catalysis in Industry (2024)

  4. No Access

    Article

    “Sowing in Science Brings a Rich Harvest for the People.” Life and Work of S. A. Fokin

    An essay on the scientific activities of the Russian organic chemist and chemical engineer Sergei Alekseevich Fokin (1865–1917) is presented. The name of the scientist is not widely known although he has made ...

    R. M. Mironenko, A. V. Lavrenov in Catalysis in Industry (2024)

  5. No Access

    Article

    Aqueous-Phase Hydrogenation of Furfural in the Presence of Supported Metal Catalysts of Different Types. A Review

    Hydrogenation of furfural in the presence of heterogeneous catalysts has recently attracted increased interest as a method for the synthesis of oxygen-containing compounds of various classes based on renewable...

    R. M. Mironenko, O. B. Belskaya… in Doklady Physical Chemistry (2023)

  6. No Access

    Article

    An Essay on the History of Catalytic Hydrogenation of Organic Compounds. From P. Sabatier and V. N. Ipatieff to the Present Days

    The essay considers historical aspects of the appearance and development of methods for catalytic hydrogenation of organic compounds, starting from the works by P. Sabatier and V.N. Ipatieff. Particular attent...

    R. M. Mironenko, A. V. Lavrenov in Catalysis in Industry (2022)

  7. No Access

    Article

    Solvent effect on the rate and direction of furfural transformations during hydrogenation over the Pd/C catalyst

    The rate and directions of transformations during the liquid-phase hydrogenation of furfural with molecular hydrogen in the presence of the 5%Pd/C catalyst (at 423 K, 3 MPa) depend substantially on the chemica...

    R. M. Mironenko, O. B. Belskaya, V. A. Likholobov in Russian Chemical Bulletin (2022)

  8. No Access

    Article

    Hydrodeoxygenation of sorbitol to gasoline-range hydrocarbons over Pt, Pd, Rh, Ru, Ni catalysts supported on tungstated alumina

    Catalytic properties of the tungstated alumina (WA) supported catalysts with different nature and content of active metal (Pt, Pd, Rh, Ru, Ni) were studied in the continuous flow hydrodeoxygenation of sorbitol...

    Y. A. Chumachenko, E. A. Buluchevskiy, E. D. Fedorova… in Biomass Conversion and Biorefinery (2021)

  9. No Access

    Article

    Carbon Black as a Support in Palladium Catalysts for Hydrogenation of Organic Compounds

    The possibility of using carbon black (CB) as a support of palladium catalysts for the selective hydrogenation of organic compounds is considered. The advantages of Pd/CB catalysts are demonstrated by examples...

    R. M. Mironenko, O. B. Belskaya, V. A. Likholobov in Solid Fuel Chemistry (2020)

  10. No Access

    Article

    Synthesis of Pd/C Catalysts: Approaches to Regulating the Structure of Active Sites toward Achieving High Selectivity in Hydrogenation of Organic Compounds

    The methods for regulating the physicochemical and catalytic properties of Pd/C compositions by varying their synthesis conditions were reviewed. The effect of the nature of the carbon support, the composition...

    R. M. Mironenko, O. B. Belskaya, V. A. Likholobov in Russian Journal of General Chemistry (2020)

  11. No Access

    Article

    Palladium Supported on Carbon Nanoglobules as a Promising Catalyst for Selective Hydrogenation of Nitroarenes

    The catalysts 1 wt% palladium supported on carbon nanoglobules (CNGs) were shown to be highly active in the liquid-phase hydrogenation of various nitroarenes and provided nearly 100% selectivity to aromatic am...

    R. M. Mironenko, O. B. Belskaya, L. N. Stepanova, T. I. Gulyaeva… in Catalysis Letters (2020)

  12. No Access

    Article

    Palladium–Ruthenium Catalyst for Selective Hydrogenation of Furfural to Cyclopentanol

    Bimetallic Pd–Ru/C catalyst was shown to be much more active in the aqueous-phase hydrogenation of furfural (473 K, 8 MPa) in comparison with both Pd/C and Ru/C catalysts. The enhanced hydrogenation activity m...

    R. M. Mironenko, O. B. Belskaya, A. V. Lavrenov, V. A. Likholobov in Kinetics and Catalysis (2018)

  13. No Access

    Article

    Effect of the reduction conditions of the supported palladium precursor on the activity of Pd/C catalysts in hydrogenation of sodium 2,4,6-trinitrobenzoate

    The study addresses the effect of the reduction conditions of palladium polynuclear hydroxo complexes (PHC) supported on the Sibunit carbon material on the dispersion of the metal particles and the activity of...

    O. B. Belskaya, R. M. Mironenko, T. I. Gulyaeva… in Russian Chemical Bulletin (2018)

  14. No Access

    Article

    Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst

    The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueous-phase hydrogenation of furfural. Under the chosen reaction conditions (temper...

    R. M. Mironenko, O. B. Belskaya, A. V. Lavrenov… in Russian Chemical Bulletin (2017)

  15. No Access

    Article

    An unusual reduction route of 2,4,6-trinitrobenzoic acid under conditions of aqueous-phase hydrogenation over Pd/Sibunit catalyst

    For the first time it was established that the catalytic hydrogenation of 2,4,6-trinitrobenzoic acid to 1,3,5-triaminobenzene can proceed via the formation of aromatic hydroxyamines and cyclohexane-1,3,5-trione t...

    R. M. Mironenko, O. B. Belskaya, V. P. Talzi, V. A. Rodionov… in Russian Chemical Bulletin (2016)

  16. No Access

    Article

    Palladium hydrogenation catalyst based on a porous carbon material obtained upon the dehydrochlorination of a chloro polymer

    The applicability of a porous carbon material obtained as a result of the “chemical” dehydrochlorination of chlorinated polyvinyl chloride as a support for palladium hydrogenation catalysts was demonstrated. T...

    R. M. Mironenko, O. B. Belskaya, V. S. Solodovnichenko… in Kinetics and Catalysis (2016)

  17. No Access

    Article

    Effect of carbon support nature and palladium content on the properties of Pd/C catalysts in hydrogenation of benzaldehyde

    In the series of studied Pd/C catalysts, the highest selectivity for benzyl alcohol formation with complete conversion of benzaldehyde was demonstrated by the sample containing 1% palladium supported on carbon...

    O. B. Belskaya, R. M. Mironenko, V. A. Likholobov in Theoretical and Experimental Chemistry (2013)

  18. No Access

    Article

    Genesis of the active-component precursor in the synthesis of Pt/Al2O3 catalysts: III. Transformations of adsorbed platinum complexes during drying

    The transformations of platinum(IV) complexes subsequent to their sorption on the support are considered. As the Pt(IV)/Al2O3 systems are dried at 25°C in daylight, their dehydration is accompanied by the replace...

    O. B. Belskaya, R. M. Mironenko, T. I. Gulyaeva, V. K. Duplyakin… in Kinetics and Catalysis (2012)

  19. No Access

    Article

    Modifying the functional cover of the γ-Al2O3 surface using organic salts of aluminum

    A method is suggested for modifying the surface properties of alumina without changing its chemical composition. The sorption of aluminum complexes with organic acid ligands on the γ-Al2O3 surface is reported. Th...

    R. M. Mironenko, O. B. Belskaya, I. G. Danilova, V. P. Talsi… in Kinetics and Catalysis (2011)