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Article
Synthesis, structure, and rearrangements of new tricarbonylchromium complexes of substituted heptalenes
Reactions of 1,2,5,6,8,10-hexamethylheptalene (1) and its bond isomer, 1,4,5,6,8,10-hexamethylheptalene (2), with tricarbonylchromium complexes L{in3}Cr(CO){in3} (L=NH{in3} and Py) have been investigated. Ther...
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Article
Synthesis and reactions of dicarbonyl (η2-indene)-η5-indenyl complexes of manganese and rhenium
Photochemical reactions of M(CO)3(η5-C9H7), where M=Mn (1) or Re (2), with indene have produced η2-indene complexes M(CO)2(η2-C9H8)(η5-C9H7), where M=Mn (3) or Re (4). Deprotonation of complex3 witht-BuOK in THF ...
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Article
Synthesis and reactions of chromium tricarbonyl complexes of 5,10-dihydroindeno[2,1-a]indene
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1-4,4a,10a-η6-5,10-Dihydroindeno[2,l-a]-indenechromium tricarbonyl was synthesized. Upon treatment with t-BuO...
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Article
Mechanism of haptotropic rearrangements in the chromium tricarbonyl complexes of naphthalene and its analogs
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The haptotropic rearrangements in the chromium tricarbonyl complexes of 1-methylacenaphthene take place predo...
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Article
First example of the n55→n5 interannular haptotropic migration of the metal-containing group in transition metal π-complexes
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Article
Synthesis of protected peptides corresponding to fragment A13–16 of human insulin