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Article
Polyoxovanadate-based metal–organic frameworks consisted of open vanadium sites for selective catalytic oxidation of sulfides
Three novel polyoxovanadate-based metal–organic frameworks (POV-MOFs), [Co2(1,4-dtzb)3]{V4O12} (V-Co-MOF1, 1,4-dtzb = 1,4-di(4H-1,2,4-triazol-4-yl)benzene], [Co3(1,3-dtzb)2]{V6O18} (V-Co-MOF2, 1,3-dtzb = 1,3-di(4
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Article
Insight into hexanuclear peroxotantalum complexes: synthesis, characterization, and efficient catalyst for amidation reaction
Polyoxometalates (POMs), large oxoanions of the group 5 and 6 elements, attract attention due to their use as oxidation-stable catalysts and ligands. Different from the well-known V, Mo, and W POMs, the group ...