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Article
Catalytic removal of tert-butyldimethylsilyl (TBS) and tetrahydropyranyl (THP) groups from protected alcohols by NO+BF4 − in methanol
An effective, catalytic method has been developed to remove TBS and THP groups from protected alcohols. TBS and THP ethers were selectively cleaved using a catalytic amount of NO+BF4 − (5 ...
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Article
Experimental evidences for stereo-promoted intermolecular C-H···O hydrogen bonding in solution
The 1H NMR data and the results of DFT quantum-chemical calculations indicate stereocontrolled formation of intermolecular C-H···O hydrogen bonds in aqueous solutions of L-(2S,3S)-2-(imidazol-1-yl)-3-methylpentan...
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Article
A novel photoinduced electron transfer reaction of N-alkylphenothiazines in carbon tetrachloride
U. V. irradiation of N-alkylphenothiazines (la—c) in carbon tetrachloride produced 3-(phenothiazin-N’-yl-carbonyl)-N’-alkylphenothiazine (2a—b) and/or 3-(N’-alkylphenothiazin-3’-yl-carbonyl) -N-alkylphenothiazine...
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Article
Kinetic studies on the single electron transfer reaction between 2, 2, 6, 6-tetramethylpiperidine oxoammonium ions and phenothiazines: the application of Marcus theory
Electron transfer reactions take place readily between 2, 2, 6, 6-tetramethylpiperidine oxoammonium ions (la,lb) and phenothiazines (2a—2g), giving corresponding nitroxides (3a,3b) and phenothiazine radical catio...