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Article
Intermolecular interactions and spin states of complexes [Fe(3-MeO-Qsal)2]Y (Y = PF6, BF4)
Compounds [Fe(3-MeO-Qsal)2]Y (Y = PF6, BF4) have been prepared by diffusion method and studied in temperature range 5–300 K by EPR and magnetic susceptibility methods. The coexistence of spatially separated high-...
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Article
Preparation and liquid-crystalline properties of mono- and binuclear complexes of Fe(III) with pentadentate Schiff’s base
Liquid-crystalline mono-and binuclear complexes of Fe(III) based on pentadentate Schiff’s base, N,N′-bis(2-hydroxy-4-octadecyloxybenzyliden)-1,7-diamino-4-azaheptane, have been prepared for the first time. The ef...
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Article
Factors affecting photoisomerization of 4-styrylpyridine
Photoisomerization of 4-styrylpyridine at different irradiation wavelengths (λ 365 and 254 nm) and in different solvents was studied by UV and 1H NMR spectroscopy. A procedure for recording the UV spectra of 4-st...
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Article
Role of Aromatic Hydrocarbons in Sediment Formation in Transformer Oil
The structural composition of fresh and aged (under model conditions) GK-grade transformer oil and petrolatum oil is studied by UV and 1 N NMR spectroscopy. Comparative experimental studies showed that sedimen...
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Article
Synthesis and photoisomerization of mesogenic 4-alkoxystyrylpyridines
Introduction of long-chain alkoxy substituents into molecules of styrylpyridines as potential ligands for photosensitive metal complexes endows them with liquid crystalline properties over a wide temperature r...
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Article
On light scattering in transformer oil
GK transformer oil is studied using the methods of UV and visible spectroscopy, dynamic light scattering, small-angle light scattering, scanning electron microscopy, and element analysis. The effect exerted on...
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Article
UV spectroscopy of GK transformer oil
A simple and efficient method is proposed for obtaining a thin layer of transformer oil in a standard cell for the recording of UV spectra. UV and visible absorption spectra of fresh, used, and aged (under mod...