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Article
Hydrogenation of Dinitrobenzenes to Corresponding Diamines Over Cu–Al Oxide Catalyst in a Flow Reactor
The catalytic hydrogenation of dinitroaromatic compounds is an important reaction for the production of phenylenediamine derivatives, which are widely used in industry. In this work, the catalytic properties o...
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Article
Selective Catalytic Hydrodebromination of 2,3,4,5-Tetrabromothiophene with Hydrogen on a Palladium Catalyst
A way of hydrodebrominating 2,3,4,5-tetrabromothiophene (1) to 3,4-dibromothiophene (2) on a 5% Pd/Sibunit catalyst is proposed. The effect of solvent, alkaline agent, temperature, and concentration of 1 on the y...
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Article
A Comparative Study of the Hydrogenation of 1,3,5-Trinitrobenzene and 2,4,6-Trinitrotoluene over a Copper–Alumina Catalyst in a Flow Reactor
The catalytic properties of a copper–alumina catalyst prepared from double layered hydroxide have been studied in the hydrogenation of 1,3,5-trinitrobenzene (TNB) and 2,4,6-trinitrotoluene (TNT) in a flow reac...
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Article
Facile method for the synthesis of oseltamivir phosphate
A ten-step scheme for the preparation of an antiviral agent, ethyl (3R,4R,5S)-4-acetylamino-5-amino-3-(pent-3-yloxy)cyclohex-1-enecarboxylate phosphate, from (-)-shikimic acid was studied. The main parameters of ...