-
Article
Two-dimensional Nitrogen-doped Mesoporous Carbon/Graphene Nanocomposites from the Self-assembly of Block Copolymer Micelles in Solution
The self-assembly of block copolymer in solution has proven to be an effective strategy for building up a wide range of nanomaterials with diverse structures and applications. This paper reports a facile self-...
-
Article
Polymer vesicle sensor through the self-assembly of hyperbranched polymeric ionic liquids for the detection of SO2 derivatives
This work reports a SO2 derivative-detecting and colorful hyperbranched polymeric ionic liquid (HBPIL) vesicle through aqueous self-assembly. By a simple anion-exchange, we achieved the combination of functional ...
-
Article
Effect of branching architecture on glass transition behavior of hyperbranched copolystyrenes: the experiment and simulation studies
By controlling the feed ratio of CMS/styrene and the polymerization time, a series of hyperbranched copolystyrenes (HBCPS) were synthesized with comparable weight-averaged molecular weights (M ...
-
Article
188Re-labeled hyperbranched polysulfonamine as a robust tool for targeted cancer diagnosis and radioimmunotherapy
Hyperbranched polysulfonamine (HPSA) is a promising biomaterial due to its highly branched spherical architecture and efficient intracellular translocation. To realize the functionalization of HPSA, both N-succin...
-
Article
Degree of branching of the hyperbranched polymers resulted from ab2 polycondensation with substitution effect
The analytical expressions of the various structural units and the average degree of branching for the hyperbranched polymers resulted from AB2 polycondensation with substitution effect were derived by the kineti...
-
Article
The amphiphilic multiarm copolymers based on hyperbranched polyester and lysine: Synthesis and self-assembly
The amphiphilic multiarm copolymers were synthesized through the modification of commercially available hyperbranched polyesters (Boltorn H40) with N-ɛ-carbobenzoxy-L-Lysine N-carboxyanhydride (ZLys-NCA). After b...
-
Article
Synthesis, crystal structure and properties of a novel di-μ2-aqua bridged binuclear manganese(III) Schiff base complex [Mn(vanen)(H2O)2]2(ClO4)2 · 2H2O
The preparation and isolation of the binuclear manganese(III) complex, [Mn(vanen)(H2O)2]2(ClO4)2 · 2H2O was accomplished by air oxidation of a solution containing H2vanen**, Et3N, and Mn(ClO4)2 · 6H2O in absolute...
-
Article
Crystal structure of [Cu2(II)(dmpa)2(p-Cl-C6H5COO)2] (Hdmpa = N,N-dimethyl-3-amino-1-propanol)
The copper complex, [Cu2(II)(dmpa)2(p-Cl-C6H5COO)2], has been prepared and its structure determined using X-ray crystallography. The dimer is a di-μ2-alkoxo complex which is a five-coordinate copper dimer with un...
-
Article
Self-assembly in transition metal complexes: structural characterization of a copper histamine nitrate [Cu(II)(him)2(NO3)2]
A new monomeric copper (II) complex with histamine (him), [Cu(II)(him)2(No3)2], has been prepared by the reaction of Cu(NO3)2 with histaminium dichloride and its structure was determined by x-ray crystallography....
-
Article
Crystal structure of [Co(bipy)(maleato) (H2O)3]·H2O (bipy = 2,2′-bipyridine)
Preparation of the mononuclear cobalt(II) complex, [Co(bipy)(maleato) (H2O)3]·H2O (1) where bipy = 2,2′-bipyridine, were accomplished by reaction of an aqueous solution containing sodium maleate and an ethanolic ...
