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Article
Synthesis, crystal structure and properties of di-μ2-alkoxo bridged binuclear manganese(III) Schiff base complexes
Preparation and isolation of the dimeric manganese(III) complex, [Mn2(Salpa)2(H2O)2Cl2] · 2DMF, (1), was accomplished by air oxidation of a solution containing MnCl2 · 4H2O, Et3N and H2Salpa** in DMF. Complex (2)
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Article
Synthesis, crystal structure and properties of a novel di-μ2-aqua bridged binuclear manganese(III) Schiff base complex [Mn(vanen)(H2O)2]2(ClO4)2 · 2H2O
The preparation and isolation of the binuclear manganese(III) complex, [Mn(vanen)(H2O)2]2(ClO4)2 · 2H2O was accomplished by air oxidation of a solution containing H2vanen**, Et3N, and Mn(ClO4)2 · 6H2O in absolute...
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Article
Crystal structure of [Cu2(II)(dmpa)2(p-Cl-C6H5COO)2] (Hdmpa = N,N-dimethyl-3-amino-1-propanol)
The copper complex, [Cu2(II)(dmpa)2(p-Cl-C6H5COO)2], has been prepared and its structure determined using X-ray crystallography. The dimer is a di-μ2-alkoxo complex which is a five-coordinate copper dimer with un...
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Article
Synthesis, crystal structure and properties of a manganese(III) Schiff-base complex: [{Mn(vanen)(Him)(H2O)}{Mn(vanen)(Him)2}](ClO4)2 · 4H2O(H2vanen = N,N′-bis(methoxysalicylidene)-1,2-diaminoethane)
A novel manganese(III) complex, [{Mn(vanen)(Him)(H2O)}(Mn(vanen)(Him)}](ClO4)2 · 4H2O [H2vanen = N,N′-bis(methoxysalicylidene)-1,2-diaminoethane], has been synthesized and characterized by elemental analysis, i.r...
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Article
Self-assembly in transition metal complexes: structural characterization of a copper histamine nitrate [Cu(II)(him)2(NO3)2]
A new monomeric copper (II) complex with histamine (him), [Cu(II)(him)2(No3)2], has been prepared by the reaction of Cu(NO3)2 with histaminium dichloride and its structure was determined by x-ray crystallography....
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Article
Crystal structure of [Co(bipy)(maleato) (H2O)3]·H2O (bipy = 2,2′-bipyridine)
Preparation of the mononuclear cobalt(II) complex, [Co(bipy)(maleato) (H2O)3]·H2O (1) where bipy = 2,2′-bipyridine, were accomplished by reaction of an aqueous solution containing sodium maleate and an ethanolic ...
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Article
Crystal structure of [Mn2(III)(salpa)2Cl2(H2O)2] (H2salpa = 1-(salicylaldeneamino)-3-hydroxypropane)
The manganese complex, (Mn2(III)(salpa)2Cl2(H2O)2], has been prepared and its structure determined using x-ray crystallography. The dimer is a di-μ2-alkoxo complex which is a six-coordinate manganese dimer with u...
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Article
Crystal structure of [Mn(II)(phen)(ClCH2COO)2]n (phen = 1,10−phenanthroline)
A new polymeric manganese(II) complex, [Mn(II)(phen)(ClCH2COO)2]n, was obtained from the reaction of Mn(ClCH2COO)2 with phen and its structure was determined by x-ray crystallography. The complex crystallizes in ...