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Article
Production of Low-Molecular-Weight Organic Components by the Microwave Pyrolysis of Peat
A facility for conducting experiments on the microwave (MW) pyrolysis of peat at a source operating frequency of 2.45 GHz has been developed. The MW pyrolysis of peat for the production of low-molecular-weight...
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Article
Synthesis and Study of Thermophysical Properties of Polystyrenes Prepared in the Presence of Conjugated α-Dinitrones Based on Glyoxal
A one-step convergent method was proposed for the synthesis of branched macromolecules in the presence of conjugated dinitrones (N,N-dimethylglyoxal dinitrone, N,N-di-tert-butylglyoxal dinitrone, and N,N- dipheny...
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Article
Structural and hydrodynamic characteristics of polystyrene synthesized in the presence of conjugated dinitrones
A series of branched high-molecular-weight alkoxyamines (HAAs) based on polystyrene of different molecular weight were synthesized using nitroxide radicals generated in situ in the presence of conjugated dinitron...
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Article
Specific features of coupling reactions of polystyrene in the presence α-dinitrones based on glyoxal
Bromine-containing polystyrene synthesized by atom transfer radical polymerization was used as a model to study coupling reactions in the presence of such free radical acceptors as conjugated dinitrones (N, N-dim...
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Article
Radical Polymerization of Styrene Mediated by Dinitrones of Various Structures
The effect of conjugated dinitrones N,N-dimethylglyoxaldinitrone, N,N-di-tert-butylglyoxaldinitrone, and N,N-diphenylglyoxaldinitrone on the radical polymerization of styrene initiated by azobis(isobutyronitrile)...
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Article
Efficiency of low-molecular-weight and high-molecular-weight alkoxyamines in the synthesis of polystyrene
The influence of the structure of high-molecular-weight alkoxyamines (obtained in situ from C-phenyl-N-tert-butylnitrone and 2-(benzylideneamino)-2-methyl-1-phenylpropanol-1-N-oxide) and their low-molecular-weigh...