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Phase Equilibria in LiYF4–LiLuF4 System and Heat Conductivity of LiY1–xLu x F4 Single Crystals

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Single crystals of LiY1–xLu x F4 (x = 0, 0.25, 0.5, 0.65, 0.9) solid solution were grown by Bridgman–Stockbarger technique. Melting points determined by DSC monotonically varied with composition from 831 to 841 K when x increased. Interval between liquidus and solidus curves is not larger 1°C. This feature extremely favors to the growth of homogeneous single crystals from melt. Heat conductivity (κ) of solid solution is lower than that of LiYF4 and LiLuF4 components. In the region 0.25 ≤ x ≤ 0.65 at 300 K, κ = 4 ± 0.1 W/(m K).

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Authors and Affiliations

  1. Kazan Federal University, Kazan, 420008, Russia

    V. V. Semashko, S. L. Korableva & A. S. Nizamutdinov

  2. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, 119991, Russia

    S. V. Kuznetsov, V. K. Ivanov & P. P. Fedorov

  3. Mordovia State University, Saransk, 430005, Russia

    A. A. Pynenkov, K. N. Nishchev & P. P. Fedorov

  4. Bryansk State University, Bryansk, 241036, Russia

    P. A. Popov

  5. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. E. Baranchikov

Authors
  1. V. V. Semashko
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  2. S. L. Korableva
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  3. A. S. Nizamutdinov
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  4. S. V. Kuznetsov
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  9. V. K. Ivanov
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Correspondence to P. P. Fedorov.

Additional information

Original Russian Text © V.V. Semashko, S.L. Korableva, A.S. Nizamutdinov, S.V. Kuznetsov, A.A. Pynenkov, P.A. Popov, A.E. Baranchikov, K.N. Nishchev, V.K. Ivanov, P.P. Fedorov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 4, pp. 405–410.

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Semashko, V.V., Korableva, S.L., Nizamutdinov, A.S. et al. Phase Equilibria in LiYF4–LiLuF4 System and Heat Conductivity of LiY1–xLu x F4 Single Crystals. Russ. J. Inorg. Chem. 63, 433–438 (2018). https://doi.org/10.1134/S0036023618040162

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  • DOI: https://doi.org/10.1134/S0036023618040162

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