Abstract
Fe (III)-2,9,16,23-tertracarboxy-phthalocyanine (Fe (Hl)-taPc) was synthesized, and bonded to polystyrene (PS) with covalence by Friedel-Crafts reaction to form a new polymer (Fe (Hl)-taPc-PS) (polymer (II)). UV-VIS and Infrared spectra indicated that Fe (III)-taPc was successfully bonded to PS. A photoreceptor device of sandwich structure consisting of alternate layers of polymer (II) and fullerene (C60) was prepared. The experiment results show that the photoconductivity of the photoreceptor is higher than that of the single-layer film of polymer (II) or C60, because of the charge-transfer effect between the layers.
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References
Shirai H., Maruayama A., Kobayashi K., et al., Functional metal-porphyrazine and their polymer 4, Makro-mol. Chem., 1980,181:575–584
Chen H. Z., Wang M., Feng L. X., et al., Synthesis and photoconductivity study of phthalocyanine polymers II, PVK-CO-CuPc (COOH)3, J. Polym. Sci. (A), 1993, 31:1165–1170
Shirai H., Yagi S., Suzuki A., et al., Functional metal-porphyrazine and their polymer 1, Makromol. Chem., 1977, 178:1889–1895
Xu Z.D., Chen W.X., Leng Y.J., et al., Photoconductivity of fullerene-doped zinc phthalocyanine, J. Mater. Sci. Lett., 1995,14:1030–1031
Chen Z. H., Li J., **e Y. M., Study on the composition and equilibrium constant of metallophthalocyanine / fullerene charge transfer complexes, Journal of **amen University (natural science), 1997,36: 740–744 (in Chinese)
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Supported by the Science Foundation of Shanghai Municipal Commission of Education (97004)
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Chen, Jm., Zhang, Jc., Shen, Y. et al. Preparation and photoconductivity of Fe-phthalocyanine Derivation and C60 composite films. J. of Shanghai Univ. 5, 156–159 (2001). https://doi.org/10.1007/s11741-001-0014-8
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DOI: https://doi.org/10.1007/s11741-001-0014-8