Abstract
New photosensitive polymer film composites based on an oligomer containing ferrocenyl and carbazolyl moieties, doped with a merocyanine dye based on ferrocene and tetranitrofluorenone, have been created, and their photoelectric properties have been studied. It has been found that these composites possess photovoltaic properties. The mechanism and features of the photovoltaic effect in the test materials are discussed.
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Davidenko, N.A., Ishchenko, A.A., and Kuvshinskii, N.G., Fotonika molekulyarnykh poluprovodnikovykh kompozitov na osnove organicheskikh krasitelei (Photonics of Molecular Semiconducting Composites Based on Organic Dyes), Kiev: Naukova Dumka, 2005.
Davidenko, N.A., Dekhtyarenko, S.V., Getmanchuk, Yu.P., Ishchenko, A.A., Kozinets, A.V., Kostenko, L.I., Mokrinskaya, E.V., Studzinskii, S.L., Skryshevskii, V.A., Skul’skii, N.A., Tretyak, O.V., and Chuprina, N.G., Fiz. Tekh. Poluprovodn. (St. Petersburg), 2009, vol. 43, no. 11, p. 1515.
Davidenko, N.A., Davidenko, I.I., Derevyanko, N.A., Ishchenko, A.A., Kostenko, L.I., Mokrinskaya, E.V., Studzinskii, S.L., Tonkopieva, L.S., and Chuprina, N.G., High Energy Chem., 2011, vol. 45, no. 3, p. 240.
Blythe, T. and Bloor, D., Electrical Properties of Polymers, Cambridge: Cambridge University Press, 2005.
Studzinsky, S.L., Mol. Crystals Liquid Crystals, 2014, vol. 589, p. 183.
Kuvshinskii, N.G., Davidenko, N.A., and Komko, V.M., Fizika amorfnykh molekulyarnykh poluprovodnikov (Physics of Amorphous Molecular Semiconductors), Kiev: Lybid’, 1994.
Kurdyukova, I.V. and Ishchenko, A.A., Russ. Chem. Rev., 2012, vol. 81, no. 3, p. 258.
Nesmeyanov, A.N., Ferrotsen i rodstvennye soedineniya (Ferrocene and Related Compounds), Moscow: Nauka, 1982.
Adirovich, E.I., Fotoelektricheskie yavleniya v poluprovodnikakh i optoelektronika (Photoelectric Phenomena in Semiconductors and Optoelectronics), Tashkent: Fan, 1972.
Nabiev, G.A., Fiz. Inzh. Pov-sti, 2008, vol. 6, no. 1/2, p. 51.
Ryvkin, S.M., Fotoelektricheskie yavleniya v poluprovodnikakh (Photoelectric Phenomena in Semiconductors), Moscow: Fizmatgiz, 1963.
Nabiev, G.A., Fiz. Tekh. Poluprovodn. (St. Petersburg), 2009, vol. 43, no. 7, p. 924.
Neporent, B.S., Elementarnye fotoprotsessy v molekulakh (Elementary Processes in Molecules), Moscow: Nauka, 1966.
Filimonov, V.D. and Sirotkina, E.E., Khimiya monomerov na osnove karbazola (Chemistry of CarbazoleBased Monomers), Novosibirsk: Nauka–Firma, 1995.
Stepnicka, P., Ferrocenes: Ligands, Materials and Biomolecules, New York: Wiley, 2008.
Pope, M. and Swenberg, C.E., Electronic Processes in Organic Crystals and Polymers, Oxford: Oxford University Press, 1999.
Pommerehne, J., Vestweber, H., Guss, W., Mahrt, R.F., Bassler, H., Porsch, M., and Daub, J., Adv. Mater., 1995, vol. 7, p. 551.
Kang, H.S., J. Comput. Chem., 2007, vol. 28, no. 2, p. 594.
Shaw-Stewart, J., Lippert, T., Nagel, M., Nuesch, F., and Wokaun, A., Appl. Phys. Lett., 2012, vol. 100, p. 203303 (4).
Barlow, S., Bunting, H.E., Ringham, C., Green, J.C., Bublitz, G.U., Boxer, S.G., Perry, J.W., and Marder, S.R., J. Am. Chem. Soc., 1999, vol. 121, p. 3715.
Kulhanek, J., Bures, F., Kuznik, W., Kityk, I.V., and Mikysek, T., A. ruzcka a, Chem. Asian J., 2013, vol. 8, no. 2, p. 465.
Salzner, U., J. Chem. Theory Comput., 2013, vol. 9, p. 4064.
Brutting, W., Physics of Organic Semiconductors, Weinheim: Wiley–VCH, 2005.
Bube, R.H., Photochemistry of Solids, New-York: Wiley, 1960.
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Original Russian Text © N.A. Davidenko, I.I. Davidenko, S.L. Studzinskii, L.I. Kostenko, A.A. Ishchenko, E.V. Mokrinskaya, L.S. Tonkopieva, 2015, published in Khimiya Vysokikh Energii, 2015, Vol. 49, No. 6, pp. 463–468.
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Davidenko, N.A., Davidenko, I.I., Studzinskii, S.L. et al. Features of the photovoltaic properties of photosemiconductor film composites based on ferrocenyland carbazolyl-containing oligomer doped with a merocyanine dye. High Energy Chem 49, 420–425 (2015). https://doi.org/10.1134/S0018143915060053
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DOI: https://doi.org/10.1134/S0018143915060053