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Efficient synthesis of bottle-brush polymers enabled by selective photoactivation strategy in NIR-induced PET-RAFT polymerization
Bottle-brush polymers possessing densely grafted side chains have special properties that are distinct from linear macromolecules. Herein, an...
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Tailoring sulfur-doped and nitrogen-defective carbon nitride nanosheets for efficient photo-controlled radical polymerizations
Despite the challenges that remain, the synergistic adjustment of various microstructures and photochemical parameters of graphitic carbon nitride...
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Photoinduced Electron-Transfer in First-Row Transition Metal Complexes
In this chapter, after a brief summary of the basic photophysical and photochemical concepts, the state of the art of the photoinduced electron...
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PET-RAFT copolymerization of vinyl acetate and acrylic acid
Photoinduced electron transfer-reversible addition–fragmentation chain transfer (PET-RAFT) polymerization of vinyl acetate (VAc) and acrylic acid...
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Metalloporphyrin-Based Biomimetic Catalysis: Applications, Modifications and Flexible Microenvironment Influences (A Review)
AbstractThe application of metalloporphyrin in the field of catalysis is one of the hotspots currently by the domestic and foreign scholars. The...
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A visible-light photoinduced controlled radical polymerization using recyclable MIL-100 (Fe) metal–organic frameworks
Controlled polymer techniques have significantly advanced thanks to using the energy of light to control radical polymerizations. Although many...
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A comparison of RAFT and ATRP methods for controlled radical polymerization
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) are the two most common...
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Interconvertible and switchable cationic/PET-RAFT copolymerization triggered by visible light
In this work, photoswitchable and interconvertible cationic/radical copolymerization was investigated by combining a Lewis acid-catalyzed cationic...
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PVA Hydrogel Functionalization via PET-RAFT Grafting with Glycidyl Methacrylate and Immobilization with 2-Hydroxypropyltrimethyl Ammonium Chloride Chitosan via Ring-Open Reaction
To solve the biofouling problem of polyvinyl alcohol (PVA) hydrogel as the artificial cornea, glycidyl methacrylate (GMA) and...
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Controlled Radical Polymerization: from Oxygen Inhibition and Tolerance to Oxygen Initiation
Molecular oxygen is a radical scavenger in both conventional and controlled radical polymerization (CRP), resulting in many time-consuming methods...
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Methods of controlled radical polymerization in the synthesis of functional polymers and macromolecular structures
In a brief review, the main trends in the modern development of the concept of controlled radical polymerization were considered and illustrated by...
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Activation and Deactivation of Chain-transfer Agent in Controlled Radical Polymerization by Oxygen Initiation and Regulation
The activation and deactivation of the chain-transfer agent were achieved by oxygen initiation and regulation with triethylborane under ambient...
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Applications of synthetic polymers directed toward living cells
Cells execute remarkable functions using biopolymers synthesized from natural building blocks. Engineering cells to leverage the vast array of...
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Visible light-induced living/controlled cationic ring-opening polymerization of lactones
Ring-opening polymerization of lactones has served as one of the most resourceful and versatile methods for the production of polyesters. However,...
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Sequence structure controllable polymerization-induced self-assembly
Polymerization-induced self-assembly (PISA) combines synthesis and self-assembly of artificial polymers in one-pot, which brings us one step closer...
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Advances in continuous polymer analysis in flow with application towards biopolymers
Biopolymers, polymers derived from renewable biomass sources, have gained increasing attention in recent years due to their potential to replace...
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Design of functional soft interfaces with precise control of the polymer architecture
Soft interfaces formed by polymer materials are important interfaces for biological systems (biointerfaces), and controlling their chemical and...
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Multiplexing fluorescent sensors for highly acidic range pH, Fe3+ ion, and temperature based on amphiphilic block copolymer
An amphiphilic block copolymer, poly(N-isopropyl acrylamide)- b -poly(N-vinyl carbazole) containing 1,8-naphthalimide and spirolactam rhodamine 6G...
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Multi-Polymerization: From Simple to Complex
Multi-polymerization in which different polymerization mechanisms are performed together serves as an essential synthetic methodology for the...
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Photochemically induced cyclic morphological dynamics via degradation of autonomously produced, self-assembled polymer vesicles
Autonomous and out-of-equilibrium vesicles synthesised from small molecules in a homogeneous aqueous medium are an emerging class of dynamically...
