Search
Search Results
-
Theoretical insight into the activity and selectivity in palladium/Ming-Phos-catalyzed three-component asymmetric synthesis of gem-diarylmethine silanes
Recently, a three-component coupling reaction for efficient construction of gem-diarylmethine silanes was developed, utilizing a Pd-Ming-Phos...
-
Polymerization of silanes through dehydrogenative Si–Si bond formation on metal surfaces
Element–element double bonds of group 14 elements can be formed in solution, but generally only by applying harsh reductive conditions using...
-
Hydrosilylation of Carbon–Carbon Multiple Bonds in Organic Synthesis
Hydrosilylation of alkenes and alkynes is the most fundamental and elegant method for laboratory and industrial synthesis of organosilicon compounds,...
-
Silicon Analogs of Unsaturated Hydrocarbons
AbstractThe existing fundamental similarities in the chemistry of structurally related carbon and silicon compounds have been demonstrated. Stable...
-
T- and Q-rich Linear Silicones from the Piers-Rubinsztajn Reaction
Most silicone polymers are linear compounds derived from dimethylsiloxane (D) monomers; the incorporation of tri- (T) and tetra-functional (Q)...
-
(Chloromethyl)alkoxyhalogenosilanes in Reaction with N-Trimethylsilyl-N-methylacetamide
AbstractThe reaction of N -trimethylsilyl- N -methylacetamide with polyfunctional silanes, namely methyl(chloromethyl)alkoxychlorosilanes and...
-
Oxidation of Triorganosilanes and Related Compounds by Chlorine Dioxide
AbstractOxidation of triethylsilane, tert -butyldimethylsilane, dimethylphenylsilane, triphenylsilane, 1,1,1,2tetramethyl-2-phenyldisilane,...
-
New polydimethylsiloxanes with bulky end groups: synthesis and properties
New polydimethylsiloxanes (PDMS) containing bulky end groups were obtained. The structure of all obtained compounds was confirmed by a combination of...
-
One-pot remote desymmetrization/peterson-olefination for the construction of silicon-stereogenic silyl ethers
Chiral silyl ethers and silanols are important synthetic intermediates and bioactive compounds. In this work, we developed a one-pot remote...
-
Role of amphiphilic organic additives in design of silica materials with ordered mesoporous structure
Templated sol–gel synthesis of silica materials with hexagonally ordered mesoporous structure was realized in the presence of amphiphilic organic...
-
Unusual selective reactivity of the rare-earth metal complexes bearing a ligand with multiple functionalities
Ligands play a key role in controlling activity of organometallic complexes so that development of new ligands to overcome the challenge is the main...
-
Single-Source-Precursor CVD: Alkoxy and Siloxy Aluminum Hydrides
Aluminum compounds with hydrogen as well as alkyl-oxy (alkoxy) or alkyl-silyl-oxy (siloxy) ligands (AlH3 -n (OR)...
-
Ni-catalyzed ligand-controlled divergent and selective synthesis
Scaffold diversity is a key feature of a compound library and plays a pivotal role in its success in biological screening. Therefore, it is highly...
-
Catalytic asymmetric silicon-carbon bond-forming transformations based on Si-H functionalization
In view of the exciting advancement on silicon-carbon bond-forming transformations achieved in the past decade, this review intends to show a unified...
-
Practical Application of Selected Functional Organosilicone Polymers
AbstractThe available information concerning the preparation and properties of modifying siloxane coatings on the surface of fibrous materials, as...
-
Trimethoxysilane Coupling Agents: Hydrolysis Kinetics by FTNIR PLS Model, Synthesis and Characterization of Fluorinated Silicone Resin
To explore the hydrolysis rules of the methoxysilane coupling agents (MSCA), the Fourier transform near infrared (FTNIR) spectroscopy combined with...
-
Synthesis and interlayer structure reconstruction of a new layered zeolitic aluminosilicate
A novel layered zeolitic aluminosilicate precursor ECNU-39(P) was hydrothermally synthesized in the fluoride system by using...
-
Stepwise on-demand functionalization of multihydrosilanes enabled by a hydrogen-atom-transfer photocatalyst based on eosin Y
Organosilanes are of vital importance for modern human society, having found widespread applications in functional materials, organic synthesis, drug...
-
One-Step Synthesis of Monosilicon-Substituted Norbornenes with Siloxane and Aryl Fragments and Their Polymerization
AbstractThree monosilicon-substituted norbornene monomers with phenyl and siloxane groups at the silicon atom are synthesized by the one-step...
-
Hydrosilylation Catalysis for One-Pot Synthesis
One-pot synthesis, including the hydrosilylation of alkenes, alkynes, carbonyl compounds, CO2, and other molecules, enables the facile synthesis of...