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New polydimethylsiloxanes with bulky end groups: synthesis and properties

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Abstract

New polydimethylsiloxanes (PDMS) containing bulky end groups were obtained. The structure of all obtained compounds was confirmed by a combination of physicochemical analytic methods. It was revealed during rheological and thermal studies of synthesized polymers that the introduction of bulky groups has a significant impact on the thermal and rheological properties of new PDMS.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Anisimov, Yu. S. Visochinskaya, M. I. Buzin, V. G. Vasil’ev, G. G. Nikiforova, A. S. Peregudov, O. I. Shchegolikhina & A. M. Muzafarov

  2. N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 28 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    Yu. S. Visochinskaya & A. M. Muzafarov

  3. N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 ul. Kosigina, 119334, Moscow, Russian Federation

    A. S. Dubovik

  4. A. N. Belozersky Institute of Physico-Chemical Biology, M. V. Lomonosov Moscow State University, 1/40 Leninskye Gori, 119991, Moscow, Russian Federation

    V. N. Orlov

Authors
  1. A. A. Anisimov
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  2. Yu. S. Visochinskaya
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  3. M. I. Buzin
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  4. V. G. Vasil’ev
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  5. G. G. Nikiforova
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  6. A. S. Peregudov
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  7. A. S. Dubovik
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  8. V. N. Orlov
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  9. O. I. Shchegolikhina
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  10. A. M. Muzafarov
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Corresponding author

Correspondence to A. A. Anisimov.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. N. Chupakhin on the occasion of his 85th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1275–1281, June, 2019.

The work was financially supported by the Russian Foundation for Basic Research (Project No. 16-03-00984).

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Anisimov, A.A., Visochinskaya, Y.S., Buzin, M.I. et al. New polydimethylsiloxanes with bulky end groups: synthesis and properties. Russ Chem Bull 68, 1275–1281 (2019). https://doi.org/10.1007/s11172-019-2553-9

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  • DOI: https://doi.org/10.1007/s11172-019-2553-9

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