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A visible-light photoinduced controlled radical polymerization using recyclable MIL-100 (Fe) metal–organic frameworks
Controlled polymer techniques have significantly advanced thanks to using the energy of light to control radical polymerizations. Although many...
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Light-responsive Self-Immolative L-glutamic Acid-based Polyester Nanoparticles for Controlled Drug Release via Passerini Three-Component Polymerization
L -glutamic acid (LA) is a bio-based, non-toxic, environmentally friendly material derived from biomass. The present study reports the application of...
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Visible light-induced living/controlled cationic ring-opening polymerization of lactones
Ring-opening polymerization of lactones has served as one of the most resourceful and versatile methods for the production of polyesters. However,...
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Features of Methyl Methacrylate Polymerization Mediated by Methylene Blue and Ethyl 2-Bromoisobutyrate under Photoirradiation Conditions
AbstractUsing methyl methacrylate polymerization as an example, the features of polymer synthesis in the presence of the catalytic system [methylene...
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Radical Polymerization
This chapter introduces the fundamental concepts of radical polymerization. Typical monomers, initiators, and transfer and termination reagents are...
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Metal-free, visible light-mediated atom transfer radical polymerization of hydroxypropyl cellulose-graft-poly(methyl methacrylate)s: effect of polymer side chains on thermo-responsive behavior of hydroxypropyl cellulose
We exploited organic photo-redox-catalyzed atom transfer radical polymerization (O-ATRP) to synthesize a thermo-responsive polymer with a narrow...
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Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents
O n-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an...
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Dual-responsive polymers synthesized via RAFT polymerization for controlled demulsification and desorption
Intelligent polymers responsive to the environment have aroused widespread interest in many applications of materials and interfaces. However,...
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Radical polymerization of methyl methacrylate in the presence of methylene blue and organobromides under visible light irradiation
The visible light-induced polymerization of methyl methacrylate in the presence of methylene blue as a photocatalyst and various bromine-containing...
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Preparation of PNIPAM-Azo by RAFT polymerization and their application in thermo- and light-responsive hydrogel
Thermo-responsive poly( N -isopropylacrylamide) with terminal azobenzene group (PNIPAM-Azo) can show distinct property changes in response to...
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Research progress in highly efficient reversible deactivation radical polymerization of vinylidene fluoride
Polyvinylidene fluoride (PVDF)-based polymers are extensively utilized in various fields such as building and large bridge coatings, lithium battery...
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Controlled radical copolymerization of fluoroalkenes by using light-driven redox-relay catalysis
Fluoroalkenes are feedstocks in the manufacture of high-performance fluoropolymers with various applications. However, the synthesis of well-defined...
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Selenium Nanoparticles Stabilized by Amphiphilic Molecular Brushes with Varying Degrees of Polymerization of Side Chains: Spectral and Structural-Morphological Characteristics
AbstractAmphiphilic molecular brushes or graft copolymers (graft-CPs) with a hydrophobic polyimide main chain and hydrophilic side chains of...
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From controlled radical polymerization of vinyl ether to polymerization-induced self-assembly
Vinyl ether (VE) was long believed to be among the monomers that could not be radically homopolymerized. Therefore, to synthesize block copolymers...
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CATase-immobilized hydrogel platform molded by photo-enzyme coupling polymerization for effectively preventing postoperative abdominal adhesion
Redox homeostasis, which is regulated by enzymes acting as regulatory valves, is crucial for maintaining the proper functioning of biomolecules and a...
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Controlling reversible complexation-mediated polymerization (RCMP) via deep eutectic solvents: fast kinetics, narrow molecular weight distribution and mechanistic insights
The exploitation of new green polymerization avenues for the effective synthesis of polymers by reversible-deactivation radical polymerization plays...
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Anatomy of Catalytic Centers in Phillips Ethylene Polymerization Catalyst
A relevant fraction of the polyethylene produced in the world (about 30%) is obtained with the Phillips process. Many efforts in the last 30 years...
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Polymerization of tetrazine-substituted diacetylenes as aggregates in suspension
Polydiacetylenes (PDAs) are conjugated polymers that have been widely exploited for their chromogenic and fluorogenic transitions upon exposure to...
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Rare earth–cobalt bimetallic catalysis mediates stereocontrolled living radical polymerization of acrylamides
The tacticity of polymers is one of the governing microstructural parameters that determines their material properties. Current methods to access...
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RAFT Dispersion Polymerization of Nitrobenzene-based Monomer and Photo-response of its Polymer Nanoparticles
The poly[ N,N -(dimethylamino) ethyl methacrylate] (PDMAEMA) macro-RAFT agent mediated dispersion polymerization of photo-responsive nitrobenzene-based...
