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Design and synthesis of thiol-terminated imidothioether oligomer as thermally latent hardener and modifier for high-performance epoxy/thiol thermosets
Conventional base-catalyzed epoxy/aliphatic thiol systems have a poor storage stability, and are impossible to be one-pot systems. A widely accepted...
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Immobilization of a cellulose carbamate-type chiral selector onto silica gel by alkyne-azide click chemistry for the preparation of chiral stationary chromatography phases
A new synthesis strategy for the preparation of cellulose derivative-based chiral selectors and the subsequent mild immobilization onto...
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Chemistry in light-induced 3D printing
In the last few years, 3D printing has evolved from its original niche applications, such as rapid prototy** and hobbyists, towards many...
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Polymer Surface Science and Adhesion Using Diazonium Chemistry
Polymer adhesionAdhesion to modified surfacesSurface is a hot, ever-progressing topic. It concerns the attachment of prefabricated polymers or... -
Dynamic Ring-chain Equilibrium of Nucleophilic Thiol-yne “Click” Polyaddition for Recyclable Poly(dithioacetal)s
We report a dynamic polymerization system based on the reversible nucleophilic Michael polyaddition of activated alkynes and dithiols. Four...
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Photocrosslinkable Antibacterial Bioadhesives Derived from Soybean Oil-Based Hydroxyurethane Methacrylates
Compared to traditional invasive techniques for wound closure, photocrosslinkable surgical adhesives with antibacterial properties offer significant...
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Facile generation of highly durable thiol-functionalized polyhedral oligomeric silsesquioxane based superhydrophobic melamine foam
In this study, a durable superhydrophobic/superoleophilic melamine foam was fabricated by a facile and rapid one-step thiol-ene click chemistry and...
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In situ preparation of thermoset/clay nanocomposites via thiol-epoxy click chemistry
A series of thermoset/clay nanocomposites are prepared by thiol-epoxy click reaction using commercially available starting compounds at ambient...
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Sulfanion-initiated open-vessel anionic ring-opening polymerization (AROP) of N-sulfonyl aziridines
Anionic ring-opening polymerization (AROP) of N -sulfonyl aziridines is an important synthetic route to linear polyethyleneimine (PEI) and its...
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Elemental Mass Spectrometry in Food and Environmental Chemistry
Analytical challenges of elemental mass spectrometry are discussed, introducing the fundamental principles of inductively coupled plasma mass... -
Vat photopolymerization 3D printing with light-responsive thiol-norbornene photopolymers
The present study highlights the synthesis of a photosensitive norbornene monomer containing an o -nitrobenzyl ester ( o -NBE) group, which undergoes...
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A Comprehensive Review on Biobased Hyperbranched Polymers
Environmental issues, including climate change and plastic pollution, have compelled scientists to look at alternatives to traditional polymers....
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CO2-Sourced Polymers: Synthesis, Property, Application
The polymeric materials could be synthesized directly from CO2 as a monomer, which are named as CO2-sourced polymers, mainly including polyurethane,... -
Preparation and Characterization of UV-curable Silicone Resin Containing Perfluorocyclobutyl Aryl Ether Groups
Silicone resin is a coating material with good performance. The improvement of its thermal stability and hydrophobicity has always been the pursuit...
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Current Trends in the Synthesis of Inorganic and Organoelement Phosphorus- and Sulfur-Containing Polymers. A Review
AbstractAn analysis of literature data on the set of reactions for the production of macromolecules with a high content of phosphorus and sulfur has...
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Holographic Polymer Nanocomposites with High Refractive Index Modulation by Do** Liquid Crystal E6M
Holographic optical elements (HOEs) based on polymer composites have become a research hot spot in recent years for augmented reality (AR) due to the...
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Preparation of Thin-Layer Graphene Using RAFT Polymerization and a Thiol-Ene Click Reaction
In this paper, functionalization of graphene is conducted through click reactions for its effective dispersion. The poly(sodium 4-styrenesolfonate)...
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Eugenol: extraction, properties and its applications on incorporation with polymers and resins—a review
The inclination of industry towards the naturally extracted raw materials is increasing to ensure the replacement of petroleum-based raw materials....
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Design of covalent adaptable networks with intrinsic flame retardancy
Thermosetting polymers crosslinked through covalent bonds are widely used in various fields due to their excellent mechanical properties and chemical...
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Epoxy vitrimer based on borate ester bond for green degradation, closed-loop recycling, and ready reprocessing
The three-dimensional network of traditional epoxy resin endows it with suitable properties, but it also presents challenges in reprocessing and...