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Thermal hazard and reaction mechanism for the preparation of epoxidized soybean oil from hydrogen peroxide
Epoxidized soybean oil (ESO) is a sustainable alternative that reduces emissions of volatile organic compounds, enhances coating and adhesion...
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Thermal hazard assessment of polyimide synthesis at different viscosities using calorimetry
The thermal hazard assessment of polyimide (PI) synthesis, including polyamide acid (PAA) and PAA imidization, was investigated owing to its...
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Thermal hazard analysis of the dual initiator-initiated styrene polymerisation with ethylbenzene as diluent
Styrene polymerization is a strong exothermic reaction, where the reactants, initiators and diluents are flammable and explosive substances. Once the...
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Thermal hazard and decomposition mechanism of p-toluenesulfonyl hydrazide
Foaming agents are widely used in the processing of polymer materials. The p -toluenesulfonyl hydrazide (TSH), as a foaming agent, generates foams...
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Fire hazard of epoxy-based transparent wood
Transparent wood is a modern bio-renewable material with great potential for both science and industrial applications. However, the fire hazard of...
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Thermal hazard assessment of 1,3-dinitrobenzene: evaluating the influence of accidental impurities on thermal hazard
To address the research gap concerning the risks associated with 1,3-dinitrobenzene (1,3-DNB) and to mitigate the potential for 1,3-DNB accidents,...
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Utilizing thermokinetic and calorimetric methods to assess the impact of an initiator on the thermal hazard of diallyl phthalate
Diallyl phthalate (DAP), a crucial raw material in producing resin materials, has been studied widely in terms of its polymerization process and...
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Thermal decomposition mechanism and hazard assessment of di-tert-butyl azodicarboxylate (DBAD)
In this work, we used C80 Micro-calorimeter and STA-FTIR-MS instrument to analyze decomposition mechanism of DBAD and evaluated the thermal hazard by...
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Evaluation of thermal hazard characteristics of building polymer initiator 2,2’-Azobis-(2-methybutyronitrile) under process conditions
The energy released by azo compounds (azo) in the decomposition process can meet the reaction threshold for promoting the building polymerization...
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Using dynamic and adiabatic methods for thermal hazard evaluation of styrene bulk polymerization initiated by AIBN
Polystyrene is a multifunctional plastic used to manufacture consumables with a wide range of applications. Some azo compounds can produce free...
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Evaluation of thermal properties and process hazard of 1-hexyl-3-methylimidazolium nitrate through thermodynamic calculations and equilibrium methods
With the continuous development of battery technology, there are new research investments in materials of various parts. In the field of...
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Study on hazard of smoke generated by mining cable fires
With the advancement of mine intelligence, mining cables find increasingly wider applications in mines. Accordingly, fire accidents caused by them...
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Enhanced hazard characterization of lithium-ion batteries subject to destructive overcharge conditions
During a failure event, electrochemical cells can exhibit such characteristics as extreme high temperatures, deflagration, fire, venting of...
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Staged thermal runaway behaviours of three typical lithium-ion batteries for hazard prevention
Thermal runaway (TR) considerably restricts the applications of lithium-ion batteries (LIBs) and the development of renewable energy sources, thus...
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Insights into reaction kinetics and autocatalysis behavior of propionic anhydride hydrolysis using real-time reaction calorimetry method
The hydrolysis reactions of anhydride have been frequently used as important model reactions for thermal hazard study. The anhydride hydrolysis...
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Thermal hazard identification of crosslinking agent BIBP using DSC test and thermokinetics simulation
Bis(tert-butylperoxy isopropyl) benzene peroxide (BIBP) is a popular bridging agent for polymerisation. However, the thermal runaway temperature and...
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Thermal hazard and pyrolysis mechanism investigation using thermal analysis coupled with quantum-chemical DFT simulation for 1-hydroxy-7-azabenzotriazole
1-Hydroxy-7-azabenzotriazole (HOAT) as a key benzotriazole derivative has been widely used in biological, chemical, and pharmaceutical fields....
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Essential hazard assessment of nitrocellulose via numerical and experimental investigation and calorimetry thermokinetic approaches
Nitrocellulose is a highly combustible substance that is extensively utilized in creating a variety of products, making the appropriate handling and...
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Thermal hazard assessment of one-step synthesis pentazolate anion by calorimetry data
Since the pentazolate anion was successfully prepared, it has gained widespread use and attention. However, due to the demands of industrial...
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Trifluoroacetaldehyde N-tosylhydrazone in [3+2] cycloaddition reaction for the synthesis of 5-(trifluoromethyl)pyrazolines
Trifluoroacetaldehyde N -tosylhydrazone used as a precursor for the in situ generation of CF 3 CHN 2 by treatment with weak bases in safe concentration...