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Organocatalysis in 1,3-Dipolar Cycloaddition Reactions (A Review)
AbstractOne of the promising directions in 1,3-dipolar cycloaddition is the implementation of these reactions under organocatalysis conditions, which...
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Asymmetric organocatalysis: from a breakthrough methodology to sustainable catalysts and processes
The evolution of modern catalytic methodologies for asymmetric organic synthesis, including transition metal and organocatalysis, is briefly...
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Assembly of versatile fluorine-containing structures via N-heterocyclic carbene organocatalysis
Owing to the unique properties of fluorine-containing moieties in the pharmaceuticals, agrochemicals and materials, several synthetic efforts ( i.e. ,...
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The 2021 chemistry Nobel laureates and asymmetric organocatalysis
The 2021 Nobel Prize in Chemistry was awarded jointly to Benjamin List and David MacMillan “for the development of asymmetric organocatalysis.” This...
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New mechanistic approach in the enamine-based asymmetric organocatalysis
During the course of my research in asymmetric organocatalysis, inversion of enantioselectivity was observed in the asymmetric aldol reactions of...
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Computational Study on the Route of Cooperative Organocatalysis Utilizing Thiourea and Halogen Bond Donor Mixture
AbstractA computational analysis of possible routes of cooperative catalysis involving hydrogen bond donating thiourea and halogen bond donating...
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Organocatalysis: A Versatile Tool for Asymmetric Green Organic Syntheses
An organocatalyst can be defined as small organic molecules, which can catalyze a wide range of important asymmetric organic transformations without...
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Stereoselective conjugate cyanation of enals by combining photoredox and organocatalysis
Precise control over the selectivity of a reaction is a fundamental target. While great advances have been obtained in achieving stereocontrol, the...
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Organocatalysis in Continuous Flow for Drug Discovery
Although organometallic chemistry has been the predominant category for the preferred catalytic transformations applied in pharmaceutical industry...
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New chiral N-heterocyclic olefin bifunctional organocatalysis in α-functionalization of β-ketoesters
N -heterocyclic olefins (NHOs) possess an electron-rich and highly polarized C=C double bond due to the donating property of nitrogen atoms. This...
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Non-isocyanate polyurethanes synthesized from terpenes using thiourea organocatalysis and thiol-ene-chemistry
The depletion of fossil resources as well as environmental concerns contribute to an increasing focus on finding more sustainable approaches for the...
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Organocatalysis Combined with Photocatalysis
Over the past decade, the combination of visible light photocatalysis and organocatalysis has made remarkable progress in modern chemical synthesis....
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Discrimination of Mobile Supramolecular Chirality: Kinetic Resolution of Mechanically Planar Chiral Rotaxanes by Organocatalysis
Among the fields of asymmetric synthesis approaching the mature science, asymmetric discrimination and catalytic synthesis of chiral supramolecules...
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Organocatalysis Combined with Photocatalysis
Over the past decade, the combination of visible light photocatalysis and organocatalysis has made remarkable progress in modern chemical synthesis....
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N-PEGylated (L)-Prolinamide: A Homogeneous, Solvent-Free, and Recyclable Catalyst for Scalable Enantioselective Aldol Reaction
The unique physicochemical properties of PEG-400 were imparted to ( L )-prolinamide to afford a homogeneous, solvent-free, recyclable organocatalyst...
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Organocatalysis in aqueous media
Even though enzymes are the cornerstones of living systems, it has so far proven difficult to deploy artificial catalysts in a biological setting....
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Aerobic Selective Oxidation of Cyclohexylbenzene Over Organocatalysis with Pairs of Nitrogenous Hydroxyl Precursors and Anthraquinones
Selective oxidation of cyclohexylbenzene is a potentially promising process in industrial application. Herein, we reported an organocatalytic system...
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Recent advances in the construction of axially chiral arylpyrroles
Catalytic enantioselective preparation of axially chiral molecules has gained considerable interest over the past decades, due to their numerous...
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Synergistic catalysis for stereocontrol of prochiral nucleophiles in palladium-catalyzed asymmetric allylic substitution
In contrast to the stereocontrol of the stereocenter at the allyl unit, the asymmetric induction of prochiral nucleophiles remains a challenge in...
