Search
Search Results
-
Hydrogenolysis
The cleavage of a bond between carbon and electronegative element, and replacing them with bonds to hydrogen is known as hydrogenolysis or reductive...
-
Polyethylene hydrogenolysis over bimetallic catalyst with suppression of methane formation
Hydrogenolysis has been explored as a promising approach for plastic chemical recycling. Noble metals, such as Ru and Pt, are considered effective...
-
Catalytic Hydrogenolysis of HMF to DMF over N-doped Molybdenum Carbide Catalyst
The effect of organic precursors on catalysts was studied and the preparation of catalyst and reaction conditions were optimized. A 91% selectivity...
-
Boron-catalysed hydrogenolysis of unactivated C(aryl)–C(alkyl) bonds
The hydrogenolysis of C–C bonds is one of the most important processes in the petroleum industry. These transformations typically rely on...
-
High-Efficient Hydrogenolysis of Xylose to Polyols Over Ni-W/CeO2 Catalysts
Catalytic hydrogenolysis of xylose to ethylene glycol (EG) and 1,2-propanediol (1,2-PG) is an important way for the high-value valorization of...
-
Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis
Carbon–carbon bond cleavage reactions, adapted to deconstruct aliphatic hydrocarbon polymers and recover the intrinsic energy and carbon value in...
-
Complete hydrogenolysis of mixed plastic wastes
The accumulation of plastic waste in the environment has led to a global crisis with severe consequences for wildlife and ecosystems. Upcycling...
-
Vapor-phase hydrogenolysis of glycerol to value-added 1,2-propanediol over copper-nickel bimetallic catalysts supported on activated carbon
In the production of biodiesel, a sustainable energy alternative to fossil fuel, surplus glycerol, is generated as a by-product. Valorization of...
-
Kinetic modeling of hydrogenolysis of glycerol to 1,2-propanediol using a chromium-free Ni–Cu–SiO2 nanocomposite catalyst
Kinetic modeling of the hydrogenolysis of glycerol was performed; a chromium-free Ni–Cu–SiO 2 nanocomposite catalyst was used to produce...
-
Predication of Selective Ring-opening Hydrogenolysis for Furfuryl Alcohol to Produce Pentanediol over Dual-atom Catalysts
Selective activation of C-O bond is of fundamental importance in the precise conversion of oxygenates into value-added compounds in an atom-economic...
-
MOFs-derived hierarchical porous carbon confining the monodisperse Ni and defective WOx for efficient and stable hydrogenolysis of cellulose to ethylene glycol
The one-pot catalytic conversion of cellulose into ethylene glycol (EG) is an attractive way of biomass utilization. However, low-cost, efficient,...
-
Colloidal metal nanocatalysts to advance orange II hydrogenolysis tracked by a microplate reader
The thermal reduction method was applied to synthesize metal nanoparticles using poly(1-vinyl-2-pyrrolidone) as an organic stabilizer to control...
-
Pd-catalyzed transfer hydrogenolysis of benzylic alcohol in acidic 2-propanol
The hydrogenolysis of 1-phenylethanol over supported palladium catalyst (Pd/SiO 2 , Pd/C, Pd/Al 2 O 3 , Pd/MgO, or Pd/hydroxyapatite) in 2-propanol under...
-
Metal–support cooperation in Al(PO3)3-supported platinum nanoparticles for the selective hydrogenolysis of phenols to arenes
The hydrogenolysis of phenols to yield arenes is of importance to the production of fine chemicals, as well as biorefinery application; however, the...
-
Hydrogenolysis of N-Benzylcyclohexylamine: A Support Specific ‘Nano Effect’
The hydrogenolysis of N -benzylcyclohexylamine (NBCA) was carried out at low temperature and pressure using series of Pd/SiO 2 catalysts having Pd...
-
Kinetic Model for the Manufacturing of 1,2-Propanediol (1,2-PDO) via Hydrogenolysis of Bio-glycerol Over Layered Double Hydroxide (LDH) Derived Cu0.45Zn0.15Mg5.4Al2O9 Catalyst in an Autoclave Reactor
Kinetic model for the formation of 1,2-propanediol via liquid-phase glycerol hydrogenolysis was developed in presence of a layered double hydroxide...
-
Phase Equilibriums of Ammonium Chloride Systems as Model Hydrogenolysis Products of Organochlorine Compounds under Naphtha Hydrotreating Conditions
AbstractThe study focuses on corrosion challenges for naphtha hydrotreating equipment (installed upstream of a reforming unit) caused by ammonium...
-
Copper-Containing Catalysts in the Liquid-Phase Hydrogenolysis of Glycerol
AbstractThe features of the liquid-phase hydrogenolysis of glycerol to 1,2-propylene glycol over Cu/Al 2 O 3 catalysts (Cu = 2–80 wt %) and individual...
-
Hydrogenolysis of glycerol to 1,3-propanediol over a Al2O3-supported platinum tungsten catalyst with two-dimensional open structure
This work investigated the effect of texture properties of the Al 2 O 3 -based catalysts on the catalytic performance for glycerol hydrogenolysis to...
-
Reaction network and kinetics for the one-pot hydrogenolysis of cellulose to ethylene glycol over NiOx-WOy-Cu/MgAl2O4
The reaction pathway and kinetics of cellulose hydrogenolysis to ethylene glycol (EG) catalyzed by nickel and tungsten combined with copper supported...
