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The helicity of Raman scattered light: principles and applications in two-dimensional materials
Raman spectroscopy has been not only a technique for characterizing the composition and lattice structure of materials, but also a platform to...
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Dynamic Helical Structures: Detection and Amplification of Chirality
A unique feature of dynamic helical, chromophoric macromolecules that enables the detection of a small imbalance in chiral guest molecules through... -
Induction and modulation of supramolecular chirality in side-chain azobenzene polymers through the covalent chiral domino effect
Induction, transfer, and modulation of intriguing supramolecular chirality were achieved in a chiral domino-type polymer system using a chiral α -end...
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Construction of Supramolecular Chirality in Polymer Systems: Chiral Induction, Transfer and Application
Chirality, commonly found in organisms, biomolecules and nature such as L -amino acids and D -sugars, has been extensively studied in chemistry and...
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Templation in Noncovalent Synthesis of Hydrogen-Bonded Rosettes
In this chapter, hydrogen-bonded assemblies based on the rosette motif are used to describe some examples of templation in noncovalent synthesis.... -
Chiral polyanilines: synthesis, chirality influencing parameters and applications
Recently supramolecular chirality has received increasing interest due to its potential applications in enantioselective sensors and chromatographic...
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Supramolecular Chiral Functional Materials
The preparation of chiral functional materials with new, improved, and interesting properties is aided tremendously by control of the spatial... -
VCD Probing Intermolecular Interactions: Molecular Crystals, Acid–Base Pairs, Host–Guest Association and Solvation
This chapter describes the VCD investigation of intermolecular interactions in molecular association. Targeted systems are molecular crystals,... -
Facile induction and stabilization of intramolecular antiparallel G-quadruplex of d(TTAGGG)n on interaction with triazine-2-imidazole ethyl amine compound and its Cu(II), Zn(II) complexes under no-salt conditions
The compounds trizImEA, Cu-trizImEA and Zn-trizImEA were synthesized and characterized by CHN, IR, NMR and mass measurements. They were interacted...
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Supramolecular Chirogenesis in Host–Guest Systems Containing Porphyrinoids
Supramolecular chirogenesis is a smart combination of supramolecular chemistry and molecular chirality resulting in effective functioning of living... -
Competition between chiral solvents and chiral monomers in the helical bias of supramolecular polymers
Solute–solvent interactions are key for the assembly and proper functioning of biomacromolecules and play important roles in many fields of organic...
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Helical polymers for biological and medical applications
Helices are the most prevalent secondary structure in biomolecules and play vital roles in their activity. Chemists have been fascinated with...
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Effect of intake manifold design on the mixing of air and bio-CNG in a port-injected dual fuel diesel engine
The awareness for an effective utilization of renewable energy and alternative fuels has been increasing. As alternative fuels, both liquid and...
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Rational Design of RN15m4 Cathelin Domain-Based Peptides from Siamese Crocodile Cathelicidin Improves Antimicrobial Activity
Antimicrobial peptides are becoming a new generation of antibiotics due to their therapeutic potential and ability to decrease drug-resistant...
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Assembling membraneless organelles from de novo designed proteins
Recent advances in de novo protein design have delivered a diversity of discrete de novo protein structures and complexes. A new challenge for the...
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Use of Circularly Polarized Infrared Light to Liquid Crystals
This chapter describes the uses of circularly polarized infrared light in the field of liquid crystals (LC). VCD determined the chirality of a... -
Enantioselective fullerene functionalization through stereochemical information transfer from a self-assembled cage
The regioselective functionalization of C 60 remains challenging, while the enantioselective functionalization of C 60 is difficult to explore due to...
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Macromolecular architectures constructed by biscalix[5]arene–[60]fullerene host–guest interactions
This focus review is designed to summarize the development of macromolecular architectures formed via biscalix[5]arene–[60]fullerene host–guest...
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Strategic optimization of conditions for the solubilization of GST-tagged amphipathic helix-containing ciliary proteins overexpressed as inclusion bodies in E. coli
Expression of affinity-tagged recombinant proteins for crystallography, protein–protein interaction, antibody generation, therapeutic applications,...
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Chiral Recognition and Resolution Based on Helical Polymers
Helical polymers have attracted a great deal of attention and been extensively investigated due to their various applications. One of the most...