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Enthalpy–Entropy Compensation in Reactions of Oxirane Ring Opening
AbstractResults are summarized from a systematic study of the enthalpy–entropy compensation effect in non-catalytic and pyridine-catalyzed reactions...
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Enthalpy–entropy compensation and isoequilibrium relationship in thermo-chemical conversion of cigarette butt filters (CBFs) based on cellulose acetate (CA): causes and effects
The aim of this study is to explain the consequences of the occurrence of enthalpy–entropy compensation (EEC) and isoequilibrium relationship during...
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Enthalpy—entropy compensation upon metal ion coordination with porphyrins: generalization for the free bases and doubly deprotonated macrocycles
Enthalpy—entropy compensation upon the coordination of zinc ions by porphyrins with various structural organizations of peripheral substitution in...
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Acid Dissociation Constants, Enthalpy, Entropy and Gibbs Energy of Bedaquiline by UV-Metric Spectral and pH-Metric Analysis
AbstractBedaquiline (trade name Sirturo) is an antibiotic used to treat pulmonary tuberculosis that is resistant to other antibiotics. The...
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Thermodynamics of water vapor sorption of fiber-reinforced starch films
The importance of adding cellulose fibers to starch films is that they are used as reinforcement, reduce the interaction of films with water, and...
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Thermodynamics of Moisture Vapor Sorption and Mechanical Characterization of Methylcellulose and Ethylcellulose Based Films
The thermodynamic parameters of moisture sorption isotherms and the mechanical behavior of ethylcellulose and methylcellulose based films were...
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Solubility of mesalazine in pseudo-binary mixtures of choline chloride/ethylene glycol deep eutectic solvent and water at 293.15 K to 313.15 K
Mesalazine (5-ASA) is a medication utilized to treat inflammatory bowel diseases involving ulcerative colitis and Crohn’s disease. Mesalazine has...
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Kinetic and thermodynamic analysis of thermo-oxidative degradation of seashell powders with different particle size fractions: compensation effect and iso-equilibrium phenomena
The issue of accumulated seashell waste has been increasingly addressed in the studies of its applicability as a secondary source of calcium...
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Water Adsorption Thermodynamical Analysis and Mechanical Characterization of Chitosan and Polyvinyl Alcohol-Based Films
Chitosan and polyvinyl alcohol films were prepared by the casting method. Moisture adsorption isotherms were obtained at 15 °C, 20 °C, 25 °C and...
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Equilibrium Solubility of Triclocarban in (Cyclohexane + 1,4-Dioxane) Mixtures: Determination, Correlation, Thermodynamics and Preferential Solvation
Equilibrium solubility of triclocarban (TCC) expressed in mole fraction in 1,4-dioxane and cyclohexane, as well, as in 19 {cyclohexane...
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Liquid Chromatography under Critical and Limiting Conditions: A Survey of Experimental Systems for Synthetic Polymers
At the interface between the entropic size exclusion separation and the enthalpydominated liquid adsorption chromatography it is possible,...
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Thermal Analysis
Thermal analysis is a series of laboratory techniques that measure physical and chemical properties of materials as a function of temperature and...
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Investigation of the solubility and thermodynamics of salicylic acid in 2-propanol and ethylene glycol/propylene glycol binary solvent mixtures at (293.15 to 313.15) K
This study aimed to measure both the solubility and thermodynamics of salicylic acid in binary solvent mixtures of (2-propanol + ethylene glycol) and...
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Thermodynamic study of lysozyme adsorption on cation-exchange monolithic adsorbent
The present study aimed to produce a macroporous monolithic cation-exchanger and evaluate the effect of temperature on the thermodynamic behavior of...
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Kinetic compensation effect of isoconversional methods
For experimental data obtained under different reaction/process conditions over time or temperature, the kinetic compensation effect (KCE) can be...
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Phase and Reaction Equilibrium, and Phase Transitions
Whilst avoiding discussions on basic thermodynamic functions which can be found in many other chemistry and engineering textbooks, this chapter...
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Investigation of the interaction of promethazine hydrochloride drug with tetradecyltrimethylammonium bromide: Impacts of hydrotropes composition and temperature
Herein, the micellization characteristics of tetradecyltrimethylammonium bromide (TTAB) and promethazine hydrochloride (PMH) mixtures have been...
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Physicochemical investigations of clouding development and physicochemical properties of Triton X-100 and levofloxacin hemihydrate mixture: influence of sodium salts composition
The study of phase separation of triton X-100 (TX-100) and levofloxacin hemihydrate (LFH) mixture in aqueous solutions of electrolytes has the keen...
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Investigation of the impacts of simple electrolytes and hydrotrope on the interaction of ceftriaxone sodium with cetylpyridinium chloride at numerous study temperatures
Herein, interactions between cetylpyridinium chloride (CPC) and ceftriaxone sodium (CTS) were investigated applying conductivity technique. Impacts...
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Comprehensive Analytical Sorption Thermodynamic (CAST) model for water vapor sorption in cellulosic materials
Water vapor sorption is a fundamental property of cellulosic materials. Numerous theoretical and empirical models have been developed to describe the...
