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Studies of Excess Electron and Hole Transfer in DNA at Low Temperatures
In this review investigations of hole and electron transfer processes in DNA after γ-irradiation at low temperatures are described. These experiments...
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Radical thioesterification via nickel-catalysed sensitized electron transfer
Multi-catalytic reaction modes have attracted widespread attention in synthetic chemistry. The merger of nickel catalysis with photoredox catalysis...
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Asymmetric photoredox catalytic formal de Mayo reaction enabled by sensitization-initiated electron transfer
Visible-light-driven photoredox catalysis is known to be a powerful tool for organic synthesis. Its occurrence critically depends on the twice...
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Proton-Coupled Electron Transfer Reactions at a Distance in DNA Duplexes
The nucleic acid analog 2-aminopurine (2AP) can be site-specifically incorporated into oligonucleotides without significantly affecting the thermal...
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Hexafluoroisopropanol-assisted selective intramolecular synthesis of heterocycles by single-electron transfer
Intramolecular amination of remote aliphatic C–H bonds via hydrogen-atom transfer reactions has become a powerful tool for accessing saturated...
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Electron transfer in protein modifications: from detection to imaging
Signal pathways participate in vital biological processes and regulate complex life activities through protein modifications. Protein modifications...
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A molecular-level mechanistic framework for interfacial proton-coupled electron transfer kinetics
Electrochemical proton-coupled electron transfer (PCET) reactions can proceed via an outer-sphere electron transfer to solution (OS-PCET) or through...
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The Mechanism of Epoxide Opening through Electron Transfer: Experiment and Theory in Concert
This review gives a description of the mechanism of reductive epoxide opening through single-electron transfer. A number of electron-transfer...
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Elucidating electron-transfer events in polypyridine nickel complexes for reductive coupling reactions
Polypyridine-ligated nickel complexes are widely used as privileged catalysts in a variety of cross-coupling reactions. The rapid adoption of these...
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Key genes of electron transfer, the nitrogen cycle and tetracycline removal in bioelectrochemical systems
BackgroundSoil microbial fuel cells (MFCs) can remove antibiotics and antibiotic resistance genes (ARGs) simultaneously, but their removal mechanism...
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Acridinedione-phthalimide conjugates: Intramolecular electron transfer and singlet oxygen generation studies for optical and photodynamic therapy applications
We reported herein the synthesis, characterization of hybrid conjugates composed of phthalimide (Phth) and acridine-1,8-diones (Acr) for optical and...
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Quenching of reactive species by Avenanthramides: theoretical insight to the thermodynamics of electron transfer
Avenanthramides (AVs) are the phytochemicals found in cereals exclusively in oats. These are widely known natural substances that have antioxidant...
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About energy and electron transfer processes in C60 /phthalocyanine films
In the present work absorption, photoluminescence excitation and emission spectra of fullerene C60, and a zinc derivative of phthalocyanine (ZnPc) in...
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Rudolph A. Marcus at 100 – theoretician of electron transfer reactions
Rudolph A. Marcus (b. 1923) Canadian-born American theoretical chemist has had a distinguished career. The period of 1956 to 1965 stands out when at...
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Theory and kinetic modeling of electrochemical cation-coupled electron transfer reactions
A simple Hamiltonian Marcus-type model for cation-coupled electron transfer reactions is introduced, and an expression for the activation energy is...
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Transcriptional regulation of living materials via extracellular electron transfer
Engineered living materials combine the advantages of biological and synthetic systems by leveraging genetic and metabolic programming to control...
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High-energy two-electron transfer in ion-atom collisions
Two-electron transfer by fast heavy nuclei from heliumlike targets is studied. A detailed sequence of comprehensive computations is carried out in a...
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Improving Indigo Reduction to Leuco-Indigo by Glucose by Means of Direct Electron Transfer and Electron Carriers of Enzymes
In this study, the reduction of indigo to leuco-indigo by glucose was improved by the use of enzymes, such as glucose oxidase (GOD) and laccase...
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One-Electron Transfer during Dimerization of Phenoxyl Radicals
AbstractThe fact that the dimerization of phenoxyl radicals involves one-electron transfer is confirmed by the performed quantum-chemical...
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DNA Electron Transfer Processes: Some Theoretical Notions
Charge motion within DNA stacks, probed by measurements of electric conductivity and by time-resolved and steady-state damage yield measurements, is...