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Comb-shaped Poly(eicosyl methacrylate) Polymer via reverse ATRP using Fe(III) complex
Reverse atom transfer radical polymerization (ATRP) of eicosyl methacrylate (EMA) has been carried out using homogeneous catalytic system...
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Picrate salts with bipyridine derivatives: intramolecular and intermolecular aspects
Here, we present the preparation and characterization of two novel picrate salts. The 2,2′-bis(pyridinium)ketone picrate, DPK-PA ( 1 ), crystallizes in...
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Cyclometallated Ruthenium Complex with 3,3',5,5'-Tetramethyl-1,1'-biphenyl-4,4'-bipyrazole and 2,2'-Dicarboxybipyridine: Synthesis, Optical Properties, and Quantum Chemical Modeling
AbstractNew complex [RuL(Dmdcbp) 2 ]PF 6 ( I ) is synthesized by the consecutive reactions of [Ru- p -cymene] 2 Cl 4 with...
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Theoretical and experimental studies of 2,2-bipyridine for nanocrystalline zinc-nickel deposition
A nanocrystalline Zn-Ni alloy with an average grain size of 25 nm was electrodeposited from an alkaline bath with 2,2-bipyridine. An effective...
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Construction and Properties of Ag-I Polymeric Clusters Attach with Nitrogen Heterocyclic Transition Metal Moiety
AbstractTwo silver cluster compounds {[Co(1,10′-phen) 3 ] 2 ‧[Ag 8 I 12 ]} ( 1 ) and {[Co(2, 2′-bipy) 3 ]‧[Ag 10 I 11 ]‧(OH)‧3DMF‧2H 2 O} ( 2 )...
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Implanted mixed ligand Ni complex of phenolic Schiff base and 2, 2’ bipyridine on MCM-41 as an efficient catalyst for Suzuki–Miyaura cross-coupling reactions: a greener approach
A new mixed ligand Ni complex of phenolic Schiff base and 2,2’ bipyridine was implanted on MCM-41 to prepare a simple and reusable catalyst. The...
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Copper(II) Complexes with 5-Nitro-2-furoic Acid: Synthesis, Structure, Thermal Properties, and Biological Activity
AbstractReaction of copper(II) acetate with 5-nitro-2-furoic acid (NO 2 -Hfur) and N-donor ligands 2,2'‑bipyridine (bpy) and pyridine (py) has...
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Photocatalytic CO2 reduction to CO by Cobalt(II) Pyridinyl-1,3,5-Triazine-Diamine complexes
The development of molecular photocatalytic systems for CO 2 reduction is a continuous challenge for chemists. Herein, the photocatalytic reductions...
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Non-covalent interactions constructor of 3D networks of Co (II) and Cu (II) complexes with pyridine ligands: systematic theoretical and experimental survey
Molecular geometries and 3D networks of two reported complexes with mixed ligands formulated as [Co(pydco)(bipy)(H 2 O) 2 ] ( 1 ) and [Cu(Hpydco)(bipy)Cl] (
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Stereospecific formation of vanadium mandelato complexes with [Fe(2,2′-bipyridine)3]2+ as a counter ion
Two vanadium complexes of mandelic acid having [Fe( bpy ) 3 ] 2+ as counterion, [Fe( bpy ) 3 ][V 2 O 4 ( rac - mand ) 2 ]·4.9H 2 O·0.1CH 3 CN ( 1 , FeV 2 L 2 ) and (H 3 O)[Fe( bpy ) 3 ]
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Rational design of cuprofullerene bipyridine nanozyme with high peroxidase-like activity for colorimetric sensing of bleomycin
The high catalytic activity of Cu-based nanozymes mainly depends on the efficient Fenton-like reaction of Cu + / H 2 O 2 , but Cu + cannot exist stably....
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Ordering a rhenium catalyst on Ag(001) through molecule-surface step interaction
Atomic scale studies of the anchoring of catalytically active complexes to surfaces may provide valuable insights for the design of new catalytically...
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Samarium and ytterbium complexes based on sterically hindered 1,2-bis(imino)acenaphthene*
Reactions of the samarium complex [(Ar BIG -bian) 2− Sm 2+ ] ( 1 ) (Ar BIG -bian is the 1,2-bis-[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene dianion)...
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Synthesis, X-ray structural analysis, antibacterial and DNA-binding studies of a lanthanum bis-(5,5′-dimethyl-2,2′-bipyridine) complex
A new complex with the formula [La(5,5′-dmbpy) 2 (NO 3 ) 3 ] (a) [where (5,5′-dmbpy = 5,5′-dimethyl-2,2′-bipyridine)] has been synthesized. The compound...
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Synthesis and Crystal Structures of Two Cd(II) Coordination Polymers Assembled by 4-Carboxymethoxy-3-phenylacrylic Acid Ligands
Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H 2 O)] n ( 1 ) and [Cd(CMOPAA)(Bipy)] n ( 2 ), (H 2 CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid,...
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The synergism of sequential paired electrosynthesis with halogen bonding activation for the cyclization of organochlorides with olefins
Reported herein is the design of a new catalytic paradigm by synergistically combining sequential paired electrosynthesis with halogen-bonding (XB)...
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Synthesis, crystal structure and battery-like studies on a new acylpyrazolone-based mixed-ligand Cu(II) complex
A new mixed-ligand Cu(II) complex, [Cu(pyr)(bpy)(OH 2 )]ClO 4 (1), was synthesized from 4-acetyl-3-methyl-1-phenyl-2-pyrazoline-5-one (H-pyr) and...
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Probing the biomolecular (DNA/BSA) interaction by new Pd(II) complex via in-depth experimental and computational perspectives: synthesis, characterization, cytotoxicity, and DFT approach
Scientists should not forget that the rate of death as a result of cancer is far more than that of other diseases like influenza or coronavirus...
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Primary processes in photophysics and photochemistry of a potential light-activated anti-cancer dirhodium complex
Photophysics and photochemistry of a potential light-activated cytotoxic dirhodium complex [Rh 2 (µ-O 2 CCH 3 ) 2 (bpy)(dppz)](O 2 CCH 3 ) 2 , where...
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Metformin-Derived Water-Soluble Cobalt Complexes: Thermal, Spectroscopic, DNA Interaction, and Molecular Docking Studies
Novel three water-soluble cobalt (II) complexes of type [Co(metf)(o-phen) 2 ]Cl 2 (1), [Co(metf)(opda) 2 ]Cl 2 (2), and [Co(metf)(2–2′bipy) 2 ]Cl 2 (3) (Metf,...
