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A green approach for the synthesis of 2-oxo-1,2,3,4-tetrahydropyrimidines through oxidative functionalization of methyl arenes/benzyl derivatives via in situ generated urea
The present work revealed a novel one-pot synthesis of 2-oxo-1,2,3,4-tetrahydropyrimidines. It involved the use of methyl arenes as a surrogate of...
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Poly(ethylene glycol) Methyl Ether Methacrylate-bonded Stationary Phase in Ion Chromatography and Its Application to Seawater Samples
A fast and simple ion chromatographic method for the determination of iodide in seawater is reported using poly(ethylene glycol) methyl ether...
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Synthesis of Acetylenic [Chloro(iodo)methyl]silanes and 2-Sulfanylbenzothiazoles Based Thereon
AbstractBromomagnesium derivatives of ethynylsilanes [Me 4– n Si(C≡CMgBr) n , n = 1–3] reacted with chloro(chloromethyl)dimethylsilane to give the...
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Effects of solid lipid nanocarrier containing methyl urolithin A by coating folate-bound chitosan and evaluation of its anti-cancer activity
BackgroundNanotechnology-based drug delivery systems have received much attention over the past decade. In the present study, we synthesized Methyl...
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Synthesis of {4-[1-(2-Fluorophenyl)-1H-thieno[3,2-c]pyrazol-3-yl]piperazin-1-yl}(1-methyl-1H-imidazol-4-yl)methanone
AbstractAn efficient synthesis of {4-[1-(2-fluorophenyl)-1 H -thieno[3,2- c ]pyrazol-3-yl]piperazin-1-yl}(1-methyl-1 H -imidazol-4-yl)methanone starting...
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Oscillatory carbonylation of poly(ethylene glycol)methyl ether acetylene. Improved model of reaction mechanism
The study presents a mathematical model of Bruk Temkin-Gorodsky Novakovic (BT-GN) reaction system employing palladium-catalyzed oscillatory...
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Synthesis and halogenation of 2-methylimidazo[1,2-a]pyridine. Antimicrobial activity of 3-bromo-2-methyl-1Н-imidazo[1,2-a]pyridinium bromide
Imidazo[1,2- a ]pyridine derivatives have been shown to possess a broad range of biological activity. 2-Amino-1-propargylpyridinium and...
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Selective sensing of thiols by aryl iodide stabilized fluorescent gold cluster through turn-off excimer emission caused by ligand displacement
AbstractHere we report fluorescence quenching based detection of selected “Thiol” molecules by employing a luminescent gold cluster through ligand...
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Improved ionic conductivity and efficiency of dye-sensitized solar cells with the incorporation of 1-methyl-3-propylimidazolium iodide
1-Methyl-3-propylimidazolium iodide (MPII) ionic liquid incorporated gel polymer electrolyte (GPE) has successfully enhanced the efficiency of a...
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Towards universal detection with 213 nm for velocity map imaging
The velocity map imaging of the methyl radical formed by 266 nm photolysis of methyl iodide using the 213 nm non-resonant multi-photon ionization...
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Additive effects of lithium halides on the tensile and rheological properties of poly(methyl methacrylate)
Lithium halides are easily dispersed in poly(methyl methacrylate) (PMMA) and lead to strong physical crosslinking with PMMA. We investigated the...
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Synthesis, Structure, and Non-Covalent Interactions of 5-Methyl-2,3-dihydrothiazolo[2,3-b]thiazolium Halides
Abstract2,3-Dihydrothiazolo[2,3- b ]thiazolium iodides and bromide have been obtained for the first time via cyclization of the corresponding...
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Regioselectivity of Alkylation of Azolo[1,5-a]pyrimidines
AbstractThe reactions of substituted 5-aminopyrazoles and 5-amino-1,2,4-triazole with 3-(ethoxymethylidene)acetylacetone, as well as with ethyl...
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Synthesis of novel 1,2,3-triazole hybrids of methyl β-orsellinate with capabilities to arrest cell cycle and induce apoptosis in breast cancer cells (MCF-7)
A total of eleven novel 1,2,3-triazole hybrids were synthesized in excellent yields from methyl β-orsellinate through a two-step protocol with...
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Iodide-enhanced palladium catalysis via formation of iodide-bridged binuclear palladium complex
The prevalence of metalloenzymes with multinuclear metal complexes in their active sites inspires chemists’ interest in the development of...
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INFLUENCE OF PRESSURE ON STRUCTURAL, ELECTRONIC, AND OPTICAL PROPERTIES OF CHOLINE IODIDE
AbstractThe influence of pressure on structural, electronic, and optical properties of choline iodide is studied within the density functional theory...
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Bimolecular reduction of carbon dioxide: double synthons for alkynes trifunctionalization
Carbon dioxide reduction, as a sustainable and versatile strategy for the access of chemical fuels, has attracted increasing attention and enormous...
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Epoxidation of Tall Oil Fatty Acids and Tall Oil Fatty Acids Methyl Esters Using the SpinChem® Rotating Bed Reactor
Tall oil fatty acids are a second-generation bio-based feedstock finding application in the synthesis of polyurethane materials. The study reported...
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Postharvest methyl jasmonate treatment inhibits blue mold decay in Ginkgo biloba seeds by inducing antioxidant and defense systems
The effects of methyl jasmonate (MeJA) treatment on the mold decay and disease resistance of Ginkgo biloba seeds in response to pathogen attack were...
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Synthesis and Transformations of 4-[2-methyl-4-(methylsulfanyl)quinolin-3-yl]butan-2-ones Substituted in the Benzene Ring
AbstractNovel hetarylquinolines containing the thiazolidine and dihydrothiazole rings were synthesized on the basis of benzene ring–substituted...