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Article
Host-aided pH-controlled substitution reaction of aryl diazonium salts and sodium azide
Aided by a host molecule, cucurbit[6]uril (CB[6]), pH-controlled substitution reaction between 4-methoxybenzenediazonium tetrafluoroborate and sodium azide was developed. The interaction of CB[6] and aryl diaz...
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Article
Open AccessPDA modification and properties of α-AlH3
We present a novel surface coating to resolve the stability of α-AlH3. Inspired by the strong chemical adhesion of mussels, the polymerization of dopamine was first introduced to coat α-AlH3 through simple situ p...
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Article
Association behavior and fluorescence quenching between cationic zinc porphyrin pendant groups on water-soluble polymers and anionic iron porphyrin guests
An amphiphilic cationic tripyridiniumylporphyrin monomer, i.e., ZnTrMPyP, was synthesized and copolymerized with acrylamide in water and dimethyl sulfoxide, respectively, to prepare the water-soluble random co...
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Chapter
Introducing Tetrazole Salts as Energetic Ingredients for Rocket Propulsion
Two tetrazole salts, hydroxylammonium 2-dinitromethyl-5-nitrotetrazolate (HADNMNT) and dihydroxylammonium 5,5′-bistetrazole-1,1′-diolate (HATO), were synthesized and characterized. HADNMNT is a new compound, w...
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Article
Ordered and layered structure of liquid nitromethane within a graphene bilayer: toward stabilization of energetic materials through nanoscale confinement
The structural characteristics involving thermal stabilities of liquid nitromethane (NM)—one of the simplest energetic materials—confined within a graphene (GRA) bilayer were investigated by means of all-atom ...
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Article
Structural characteristics of liquid nitromethane at the nanoscale confinement in carbon nanotubes
The stability of energetic materials confined in the carbon nanotubes can be improved at ambient pressure and room temperature, leading to potential energy storage and controlled energy release. However, the m...
