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Article
Highly efficient catalyst for 1,1,2-trichloroethane dehydrochlorination via BN3 frustrated Lewis acid-base pairs
In this study, a novel non-metallic carbon-based catalyst co-doped with boron and nitrogen (B,N) was successfully synthesized. By precisely controlling the carbonization temperature of a binary mixed ionic liq...
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Article
Graphdiyne anchoring to construct highly dense palladium trimer active sites for the selective hydrogenation of acetylene
Semi-hydrogenation of acetylene is of growing interest and popularity but subjects to a major challenge in selective hydrogenation to ethylene. Here, we report a strategy that uses graphdiyne (GDY) as a carrie...
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Article
Open AccessInteractions between atomically dispersed copper and phosphorous species are key for the hydrochlorination of acetylene
Vinyl chloride, the monomer of polyvinyl chloride (PVC), is industrially synthesized via acetylene hydrochlorination. Thereby, easy to sublimate but toxic mercury chloride catalysts are widely used. It is impe...
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Article
Adsorption Behavior and Electron Structure Engineering of Pd-IL Catalysts for Selective Hydrogenation of Acetylene
Develo** the catalytic activity and selectivity of palladium (Pd) catalysts for acetylene hydrogenation is key importance in the chemical industry and remains a challenge to this day. Here, the catalytic per...