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Article
Living/controlled polymerization of vinylpyridines into sequence-regulated copolymers by Lewis pair
The poly(vinylpyridine) (PVP) based (co)polymers are of particular interest in materials science, due to their multifunctionality and diverse applications. So far, there is no report on the sequence-regulated ...
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Article
Polymer Science
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Article
High Performance Polylactide Toughened by Supertough Polyester Thermoplastic Elastomers: Properties and Mechanism
It is a challenge to develop a biodegradable toughener to toughen polylactic acid (PLA) with both high strength and high toughness, since toughness and strength are mutually exclusive. Here, a series of superto.....
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Article
Research progress in the living/controlled polymerization of (meth)acrylate monomers by Lewis pair
Lewis pair polymerization (LPP) has demonstrated its unique advantages, such as high activity, high stability, and adjustable variability, towards the polymerization of (meth)acrylate monomers in comparison wi...
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Article
Recyclable cyclic bio-based acrylic polymer via pairwise monomer enchainment by a trifunctional Lewis pair
The existing catalyst/initiator systems and methodologies used for the synthesis of polymers can access only a few cyclic polymers composed entirely of a single monomer type, and the synthesis of such authenti...
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Article
Open AccessDirect synthesis of sila-benzoazoles through hydrosilylation and rearrangement cascade reaction of benzoazoles and silanes
Sila-isosteres have attracted increasing attention due to their potential application in a variety of fields and their different properties compared to their carbon-containing analogs. However, the preparation...
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Article
Open AccessDual-initiating and living frustrated Lewis pairs: expeditious synthesis of biobased thermoplastic elastomers
Biobased poly(γ-methyl-α-methylene-γ-butyrolactone) (PMMBL), an acrylic polymer bearing a cyclic lactone ring, has attracted increasing interest because it not only is biorenewable but also exhibits superior p...
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Chapter
Polymerization of Nonfood Biomass-Derived Monomers to Sustainable Polymers
The development of sustainable routes to fine chemicals, liquid fuels, and polymeric materials from natural resources has attracted significant attention from academia, industry, the general public, and govern...
