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Article
Segmental order and dynamics of polymer chains confined in block copolymer lamellar mesophases: NMR and dielectric relaxation studies
The PDMS lamellar sublayers of a poly(styrene)-poly(dimethylsiloxane) diblock (PS-PDMS) and PS-PDMS-PS triblocks are investigated by NMR and dielectric spectroscopy. Some segments of the confined PDMS chains d...
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Article
Hole nucleation in thin diblock copolymer films
This paper reports an experimental study of a homogeneous nucleation process in the direct space, using an atomic-force microscope. Nucleated patterns are holes in a thin diblock copolymer film. The formation ...
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Article
Chain segment ordering in lamellar sublayers of block copolymers: A NMR study
The chain segment dynamics in the bulk lamellar phase of polystyrene-polydimethylsiloxane (PS-PDMS) block copolymers has been probed by NMR. The experiments were performed on a PS-PDMS diblock and on a PS-PDMS...
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Article
Monolayers of diblock copolymer at the air-water interface: the attractive monomer-surface case
We have studied both experimentally and theoretically the surface pressure isotherms of copolymers of polystyrene-polyethyleneoxide (PS-PEO) at the air-water interface. The SCMF (single chain mean-field) theor...
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Article
Coalescence in 2 dimensions: experiments on thin copolymer films and numerical simulations
This paper presents on one hand the experimental study of the coalescence kinetics of two closed bidimensional fluid domains at the surface of a multilayered dibloc copolymer film, and on the other hand a nume...
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Chapter and Conference Paper
Lamellar composite magnetic materials
Synthesis of lamellar auto-assemblies of symetric PS-PBMA copolymers, doped by magnetic nanoparticles is described. As soon as particles are coated by a grafted PS layer, they can be confined in the PS layer o...
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Article
A lower critical ordering transition in a diblock copolymer melt
DIBLOCK copolymers, comprised of two distinct homopolymers covalently bonded together at one end, undergo a transition on cooling from a state in which the segments of the blocks are homogeneously mixed to one...
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Chapter
Dynamics of PS-PMMA diblock copolymers in toluene
The dynamic behaviour of two polystyrene-polymethylmethacrylate (PS-PMMA) diblock copolymers has been studied in toluene by quasielastic light scattering in the vicinity and above the overlap concentration C* of ...
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Article
Characterization of block copolymers by size exclusion chromatography
Poly(ethyl methacrylate-b-deuterated methyl methacrylate), poly(styrene-b-methyl methacrylate), and poly(styrene-b-dimethylsiloxane)diblock copolymers have been characterized by means of size exclusion chromat...
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Chapter
Study of Copolymer-Homopolymer Blends
Some years ago, we started studying the structure and thermodynamics of binary and ternary copolymer-homopolymer blends. Two aspects have been developped. The first one concerns the investigation of demixing i...
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Article
Study of the structure of block copolymer-homopolymer blends using small angle neutron scattering
The structure of “dilute solid solutions” of poly(styrene-b-butadiene) diblock copolymers within a matrix of polybutadiene has been studied using small angle neutron scattering. Experimental curves exhibit sev...
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Article
Synthese und Charakterisierung der Dreiblockeopolymeren verschiedener Alkylmethacrylate
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Article
Untersuchung der Emul-gierwirkung der Blockcopolymeren Polystyrol/Polyvinyl-2-pyridiniumchlorid und Polyisonren/Polyvinyl-2-pyridiniumchlorid
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Article
Kristallisation von Polyoxyäthylen in Blockcopolymeren. 2. Mitt. Untersuchung der Struktur und der Textur
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Article
Kristallisation von Polyoxyäthylen in Zweiblock-Copolymeren. 1. Mitt. Dilatometrisches Studium
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Article
Synthese und Charakterisierung der Blockcopolymeren Polyalkylmethacrylat/Polyäthylenoxid
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Article
Synthese und Charakterisierung der Blockeopolymeren Polystyrol/Polydimethylsiloxan und Polyisopren/Polydimethylsiloxan
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Article
Structure of mesomorphic phases observed with block copolymers of different alkyl methacrylates