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Article
Highly delocalized endohedral metal in Gd@C2v(9)-C82 metallofullerenes co-crystallized with α-S8
A new Gd@C2v(9)-C82·2.5(S8)·0.5(CS2) co-crystal was prepared for the first time and characterized by single-crystal X-ray diffraction (XRD). The analysis clearly showed that, even though the C2v(9)-C82 cage is fu...
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Article
Clusterphene: A new two-dimensional structure from cluster self-assembly
Since the advent of graphene in 2004, two-dimensional (2D) materials had ignited the development of fascinating functional materials for almost 20 years. Currently, the main members of 2D materials family are ...
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Article
Confined interface engineering of self-supported Cu@N-doped graphene for electrocatalytic CO2 reduction with enhanced selectivity towards ethanol
Electroreduction of greenhouse gas CO2 into value-added fuels and chemicals provides a promising pathway to address the issues of energy crisis and environmental change. However, the regulations of the selectivit...
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Article
Open AccessRemote substituent effects on catalytic activity of metal-organic frameworks: a linker orbital energy model
The Hammett equation is commonly used to theoretically depict the remote electronic effects of substituents on catalytic activities of metal nodes of metal-organic frameworks (MOFs). However, the application o...
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Article
Large π-conjugated indium-based metal-organic frameworks for high-performance electrochemical conversion of CO2
The active site engineering of electrocatalysts, as one of the most economical and technological approaches, is a promising strategy to enhance the intrinsic activity and selectivity towards electrochemical CO2 r...