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Article
Large π-conjugated indium-based metal-organic frameworks for high-performance electrochemical conversion of CO2
The active site engineering of electrocatalysts, as one of the most economical and technological approaches, is a promising strategy to enhance the intrinsic activity and selectivity towards electrochemical CO2 r...
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Article
Open AccessRemote substituent effects on catalytic activity of metal-organic frameworks: a linker orbital energy model
The Hammett equation is commonly used to theoretically depict the remote electronic effects of substituents on catalytic activities of metal nodes of metal-organic frameworks (MOFs). However, the application o...
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Article
Confined interface engineering of self-supported Cu@N-doped graphene for electrocatalytic CO2 reduction with enhanced selectivity towards ethanol
Electroreduction of greenhouse gas CO2 into value-added fuels and chemicals provides a promising pathway to address the issues of energy crisis and environmental change. However, the regulations of the selectivit...
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Article
Clusterphene: A new two-dimensional structure from cluster self-assembly
Since the advent of graphene in 2004, two-dimensional (2D) materials had ignited the development of fascinating functional materials for almost 20 years. Currently, the main members of 2D materials family are ...
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Article
Open Accesseg occupancy as an effective descriptor for the catalytic activity of perovskite oxide-based peroxidase mimics
A peroxidase catalyzes the oxidation of a substrate with a peroxide. The search for peroxidase-like and other enzyme-like nanomaterials (called nanozymes) mainly relies on trial-and-error strategies, due to th...
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Article
Highly delocalized endohedral metal in Gd@C2v(9)-C82 metallofullerenes co-crystallized with α-S8
A new Gd@C2v(9)-C82·2.5(S8)·0.5(CS2) co-crystal was prepared for the first time and characterized by single-crystal X-ray diffraction (XRD). The analysis clearly showed that, even though the C2v(9)-C82 cage is fu...
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Chapter
Fullerenes for Cancer Therapy and Bioimaging
Chemical derivatives of fullerene and endohedral metallofullerenes (EMFs) not only keep some of the physicochemical properties of their parent molecules, but can also have water solubility and biocompatibility...
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Article
Fullerenes and their derivatives as inhibitors of tumor necrosis factor-α with highly promoted affinities
Tumor necrosis factor-α (TNF-α) is a cell signalling protein involved in systemic inflammation in infectious and other malignant diseases. Physiologically, it plays an important role in regulating host defence...