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Article
Synthesis of functional polyisobutene I. Copolymerization of isobutene with 4-vinylbenzyl N,N-diethyldithiocarbamate
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Article
The role of complexation in living cationic polymerization with Lewis acid/ester systems
Higashimura reported living cationic polymerization by the CH3OOOEt/AlEtCl2/C6H5CH3 /IBVE system, however, the mechanism was obscure and the high mole ratio of CH3OOOEt/ AlEtCl2 (50/1) was unusual. To elucidat...
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Article
The synthesis of chlorine-terminated telechelic polyisobutylene
In synthesizing chlorine-terminated telechelic polyisobutylene (PIB) with a p-DCCCp-dichlorocumene/BCl3/CH2Cl2 system, it is found that cycloalkylation occurs parallel with propagation. The factors leading to cyc...
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Article
The synthesis of chlorine-terminated telechelic polyisobutylene
This paper deals with chain transfer reactions, primarily to monomer and to inifer (p-DCC/BCl3) in the carbocationic polymerization of isobutylene (IB). It is found that the MW and functionality of the polymer de...