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  1. No Access

    Article

    Synthesis and crystal structure of π complex of copper(I) chloride with diallyl trisulfide 2CuCl · DATrS

    Crystals of the π complex 2CuCl·DATrS (DATrS = diallyl trisulfide) were prepared by ac electrochemical synthesis and studied by X-ray diffraction. The crystals are monoclinic, space group C2, Z = 2, a = 12.737(1)...

    N. F. Salivon, V. V. Olijnik, A. A. Shkurenko in Russian Journal of Coordination Chemistry (2007)

  2. No Access

    Article

    Synthesis and crystal structure of copper halide complexes with triethylallylammonium (teaa) chloride: [(teaa)Cu 3 I Cl4], [(teaa)Cu 3 I Br3.86Cl0.14], and (teaa)2CuIICl4

    The results of X-ray diffraction analysis of novel triethylallylammonium chloride compounds with copper(I) chloride, copper(I) bromide, and copper(II) chloride are reported. The [(CH3CH2)3(CH2=CHCH2xN]Cu ...

    T. P. Lenkivska, V. V. Olijnik, V. N. Davydov in Journal of Structural Chemistry (2004)

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    Article

    Synthesis and Crystal Structure of the π-Complex 5CuCl⋅Si(O–CH2–CH=CH2)4

    This paper discusses the results of synthesis and X-ray diffraction analysis (DARCH single crystal diffractometer, MoKα radiation) of a π-complex of copper(I) chloride with tetraallyloxysilane 5CuCl⋅Si(O–CH2–CH=C...

    V. V. Olijnik, T. P. Korsak, V. N. Davydov in Journal of Structural Chemistry (2001)

  4. No Access

    Article

    Structure effects of weak interactions in heterodesmicπ-complexes of copper(I)

    Structural effects: disordering, twinning, polymorphism, and morphotropism due to substitution of halide atoms are considered using the results of X-ray diffraction analysis of 18 olefinic π-complexes of Cu(I)...

    V. V. Olijnik in Journal of Structural Chemistry (1998)

  5. No Access

    Article

    Combination of ionic and metal-olefin bonds in crystalline copper(I) π-complexes

    The ionic field effect on metal-olefin π-binding is considered for 24 Cu(I) compounds based on X-ray diffraction data. Structural features due to Cu…(C=C)−H…An and N−H…An bridges in cationic and zwitterionic π...

    V. V. Olijnik, E. A. Goreshnik in Journal of Structural Chemistry (1994)

  6. No Access

    Article

    Copper(I) nitrate π-complexes. Crystal structure of a novel modification of [Cu((CH2=CH−CH2)2NH)]NO3

    V. V. Olijnik, M. G. Myskiv, Ya. E. Filinchuk… in Journal of Structural Chemistry (1994)

  7. No Access

    Article

    Copper(I) hexafluorosilicateπ-complexes with allylammonium salts. Synthesis and crystal structure of [CuOOCH·C3H5NH3]2SiF6 and [Cu2Cl3·2C3H5NH3]2SiF6

    Two novel copper (I) π-complexes containing the SiF 6 2− anion have been synthesized and studied by X-ray structure analysis. The crystals of the first title c...

    V. V. Olijnik, E. A. Goreshnik, V. K. Pecharsky… in Journal of Structural Chemistry (1994)

  8. No Access

    Article

    Copper(I) nitrate π-complexes. Synthesis and crystal structure of CuNo3(CH2=CH-CH2)2NCN

    We have carried out X-ray structure analysis (a DARCH diffractometer, Mokα radiation, 1430 independent reflections with |F|≥4|σ(F)|, 2ϕ≤56°, R=0.0295) of a novel copper(I) nitrate π-complex with diallyl cyanamide...

    V. V. Olijnik, E. A. Goreshnik, M. G. Myskiv… in Journal of Structural Chemistry (1994)

  9. No Access

    Article

    Crystal structure of copper(I) chloride π-complexes with diallylamine: (C6H12N)2Cu7Cl9·H2O and 2CuCl·C6H11N

    For the first time we have synthesized and studied by X-ray structural analysis two novel copper(I) chloride π-complexes with diallylamine (DAA): [H(DAA)]2Cu7Cl9·H2O (D) and 2CuCl·DAA (E). Compound D is isostruct...

    V. V. Olijnik, M. G. Myskiv, V. K. Pecharskii in Journal of Structural Chemistry (1993)